Heterocyclicamides of hindered 3,5-dialkyl-4-hydroxybenzoic acids and use as light stabilizers in polyolefins
AssigneeAmerican Cyanamid Company
InventorsJohn Christian Oppelt, Peter Vincent Susi
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Abstract
Compounds of the formula: ##STR1## WHEREIN R.sub.1 and R.sub.2 are each branch-chain alkyl of 3 to 8 carbon atoms and -Het is a nitrogen-containing heterocyclic moiety attached to the carbonyl carbon atom through a heterocyclic nitrogen are useful as light stabilizers in polyolefins. They may be prepared (a) by reacting the 3,5-dialkyl-4-hydroxybenzoyl chloride with the appropriate heterocyclic amine in the presence of an acid acceptor or (b) by reacting the corresponding benzoic acid with the appropriate heterocyclic amine in the presence of a carbodiimide as dehydrating agent.
Claims10
A compound of the formula:
- ##STR3## wherein R.sub.1 and R.sub.2 are each branch-chain alkyl of 3 to 8 carbon atoms and -Het is a nitrogen-containing heterocyclic moiety attached to the carbonyl carbon atom through a heterocyclic nitrogen.
A polyolefin stabilized against the deteriorating effects of light by having incorporated therein an effective amount of a light stabilizer of the formula:
- ##STR4## wherein R.sub.1 and R.sub.2 are each branch-chain alkyl of 3 to 8 carbon atoms and -Het is a nitrogen-containing heterocyclic moiety attached to the carbonyl carbon atom through a heterocyclic nitrogen.
Dependencies are inferred from the claim text.