Cell and process for electrolyzing aqueous solutions using a porous metal separator
AssigneeOlin Corporation
InventorsIgor V. Kadija, Byung K. Ahn
Life of this patent
Estimating the term…
Loading patent…
AssigneeOlin Corporation
InventorsIgor V. Kadija, Byung K. Ahn
Estimating the term…
Electrolysis of alkali metal chloride solutions to produce chlorine and alkali metal hydroxides is accomplished in a cell comprising an anode compartment, a cathode compartment, a cation permeable divider separating the anode compartment from the cathode compartment, where the anode compartment contains a porous metal separator. The porous metal separator is comprised of a porous plate of, for example, a valve metal having a porosity of from about 30 to about 75 percent and an air flow value of from about 0.1 to about 60 CFM. The anode separator is positioned in the anode compartment so it is spaced apart from the cation permeable divider and from the anode. During electrolysis, an alkaline brine zone is formed between the porous metal separator and the cation permeable divider which increases the service life of the cation permeable divider. In addition, the porous metal separator provides improved chlorine gas separation properties.
A cell for electrolyzing alkali metal chloride solutions comprised of an anode compartment, a foraminous metal anode in said anode compartment, a cathode compartment, a cathode in said cathode compartment, a cation permeable divider separating said anode compartment from said cathode compartment, and a porous metal separator positioned in the anode compartment between said foraminous metal anode and said cation permeable divider.
A process for operating an electrolytic cell for alkali metal chloride solutions, said cell having an anode compartment containing a foraminous metal anode, a cathode compartment containing a cathode, a cation permeable divider separating said anode compartment from said compartment, said process which comprises electrically disconnecting said cell, placing a porous metal separator between said anode and said cation permeable divider, and resuming electrolysis within the cell.
Dependencies are inferred from the claim text.