Process for producing magnesium utilizing aluminum metal reductant
AssigneeEthyl Corporation
InventorsJames D. Johnston, Robert N. Sanders, James M. Wood, Jr.
Life of this patent
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Abstract
Magnesium metal is produced by the reaction of aluminum metal with a calcium magnesium aluminate slag or with magnesium oxide in the presence of such slag, wherein the silicon dioxide content of the slag is maintained at five weight percent or less. An excess of aluminum metal relative to the amount of magnesium oxide is employed thereby obtaining a high conversion of the magnesium oxide to magnesium metal.
Claims19
A process for production of magnesium in a reaction-condensation system having a reducing furnace zone and a condensation zone, comprising reacting in the reducing furnace zone aluminum metal containing at least 80 weight percent aluminum and a calcium magnesium aluminate slag or magnesium oxide in the presence of said slag containing not more than five weight percent silicon dioxide, the amount of aluminum metal fed into the reducing furnace zone being in excess of the stoichiometric amount of aluminum required to react with the magnesium oxide fed into the reaction zone, and slag removed therefrom contains about 6-16 weight percent magnesium oxide, carrying out the reaction at a temperature of about 1500.degree.-1700.degree. C at a pressure of about 0.5-2.0 atmospheres, maintaining the silicon dioxide content and the magnesium oxide content of the molten oxidic slag in the reaction zone at least as low as five weight percent and about 6-16 weight percent, respectively, evolving magnesium vapor from the reaction zone to the condensation zone, and condensing and recovering the magnesium as a product.
In a process for producing magnesium by reaction of magnesium oxide with aluminum in a reaction-condensation system and utilizing a molten oxidic slag, the improvement therein, wherein the aluminum has a purity of at least 80 weight percent, the amount of aluminum metal fed into the reaction zone is from 5 to 100 percent in excess of the stoichiometric amount of aluminum required to react with the magnesium oxide, the silicon dioxide content and the magnesium oxide content of the molten oxidic slag is maintained at less than about five weight percent of said slag and about 6-16 weight percent of said slag, respectively.
A process for the production of magnesium metal in a reaction-condensation system having a reducing furnace zone and a condensation zone, comprising preparing and melting in the reaction zone a calcium magnesium aluminum oxide slag of the following weight percent composition:
- ______________________________________ Calcium oxide (CaO) 30 - 65 Aluminum oxide (Al.sub.2 O.sub.3) 28 - 64 Magnesium oxide (MgO) 6 - 16 Silicon dioxide (SiO.sub.2) .ltoreq.5 ______________________________________
- reacting with the molten oxidic slag in the reaction zone an aluminum metal of at least 80 weight percent purity, the amount of the aluminum metal being from five percent to 100 percent in excess of the amount of aluminum required to react stoichiometrically with the magnesium oxide, carrying out the reaction at a temperature of about 1500.degree.-1700.degree. C and at a pressure of about 0.5-2.0 atmospheres, periodically withdrawing molten oxidic slag from the reaction zone, maintaining the silicon dioxide content and the magnesium oxide content of the molten oxidic slag in the reaction zone and the molten oxidic slag withdrawn therefrom at five weight percent or less and about 6-16 weight percent, respectively, evolving magnesium vapor from the reaction zone to the condensation zone and recovering magnesium metal as a product.
Dependencies are inferred from the claim text.