Reactive dyestuffs containing urea alkylene linkage between chromophore and reactive radical
AssigneeBayer Aktiengesellschaft
InventorsHans-Samuel Bien, Wolfgang Harms
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Abstract
Dyestuffs are disclosed having the formula ##STR1## in which W is a reactive radical; D is the radical of an organic dyestuff; X.sub.1 is hydrogen or alkyl; X.sub.2 and X.sub.3 are hydrogen, alkyl, cycloalkyl, aralkyl or aryl; or X.sub.2 and X.sub.3 together are alkylene; Alkylene is C.sub.1 -C.sub.6 -alkylene or cycloalkylene; and n is 0 or 1. The dyestuffs are used in the dyeing of textile materials containing hydroxyl groups and nitrogen, especially natural and regenerated cellulose, wool, silk, synthetic polyamide fibers and synthetic polyurethane. The dyeings obtained are, in general, distinguished by good to very good fastness properties, especially by excellent wet fastness.
Claims14
Reactive dyetuff of the formula ##STR333## in which W is a heterocyclic or aliphatic fiber reactive radical capable of reacting with an amino, amido or hydroxyl group on a fiber;
- which is bound to ##STR334## by a carbon atom on W;
- D is a radical of an aromatic ring containing organic dyestuff which is bound to --(CH.sub.2).sub.n -- by an aromatic carbon on D;
- X.sub.1 is hydrogen;
- C.sub.1 -C.sub.4 -alkyl;
- or C.sub.1 -C.sub.4 -alkyl substituted by hydroxyl, sulfo or sulfato;
- X.sub.2 and X.sub.3 are hydrogen;
- C.sub.1 -C.sub.4 -alkyl;
- C.sub.1 -C.sub.4 -alkyl substituted by hydroxyl, sulfo or sulfato;
- cyclohexyl;
- phenyl;
- benzyl;
- phenethyl;
- or cyclohexyl, phenyl, benzyl or phenethyl substituted by hydroxyl, sulfo, carboxy, sulfamoyl or carbamoyl;
- or X.sub.2 and X.sub.3 together are --CH.sub.2 --CH.sub.2 --;
- Alkylene is C.sub.1 -C.sub.6 -alkylene, --CH.sub.2 --CH--(OH)--CH.sub.2 -- or cyclohexylene;
- and n is 0 or 1.
Dyestuff of the formula ##STR338##
Dyestuff of the formula ##STR339##
Dyestuff of the formula ##STR340##
Dependencies are inferred from the claim text.