Pyrolysis compositions from silver salts of polycarboxylic acids
AssigneeThe Standard Oil Company
InventorsEllis K. Fields, Wilford J. Zimmerschied, David A. Palmer
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Abstract
High surface area silver olefin oxide catalysts with orderly distribution of pore size are prepared by pyrolysis of silver salts of di- and polycarboxylic acids or mixtures thereof to carbon-like polymers containing silver, followed by combustion of the carbonaceous material. The resulting unsupported or supported silver catalysts are useful for oxidations, cyclizations, isomerizations, and cracking. The carbon-like polymers containing silver, before combustion of the carbonaceous material, find utility as bactericides and catalysts. Extraction of the silver yields high surface area carbon adsorbents of predetermined structure.
Claims17
A process for producing high surface area compositions with predetermined structure which comprises pyrolyzing at a decomposition temperature within the range of from about 200.degree. to 500.degree. C polysilver salts of polycarboxylic acids containing two to eight carboxyl groups comprising at least one member selected from the group consisting of aromatic polycarboxylic acids and heterocyclic polycarboxylic acids.
Dependencies are inferred from the claim text.