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US 4,065,368 AGranted
Printed circuit cover coating comprising an ultraviolet radiation sensitive acrylic resin
AssigneeBell Telephone Laboratories, Incorporated
InventorKenneth Allan Holtzman
Life of this patent
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Abstract
A flexible photopolymerizable resin is prepared in a two-stage process by the esterification of castor oil which chlorendic anhydride to yield a chlorendic anhydride half ester and the subsequent reaction of the half ester with a reagent having acrylic functionality, a cure retardant and an acrylic functional monomer. The resultant acrylic ester evidences superior insulation resistance during aging.
Claims8
Method for the preparation of photopolymerizable acrylic resin which comprises the steps of:
- a. esterifying castor oil with chlorendic anhydride in the presence of an amine catalyst at a temperature within the range of 120.degree.-150.degree. C for a time period ranging from 16-2 hours, the lower temperatures corresponding with the longer reaction times and the converse, so yielding a chlorendic anhydride half ester,
- b. admixing the resultant ester with a cure retardant, from 5 to 20 parts per 100 parts of resin of an acrylic functional monomer selected from the group consisting of methyl acrylate, butyl acrylate, ethyl hexyl methacrylate, alkyl acrylate, and methyl methacrylate, and a reagent having acrylic functionality, selected from the group consisting of glycidyl acrylate, glycidyl methacrylate and a mixture of glycidyl methacrylate and butyl glycidyl ether, said reagent being employed in an amount sufficient to assure that at least 50% of the carboxyl groups present in the ester system are reacted therewith, so yielding an acrylic ester, and
- c. exposing the acrylic ester to a source of ultraviolet radiation for a time peroid sufficient to effect curing thereof.
Dependencies are inferred from the claim text.