Method of making solid fertilizer herbicide granules
AssigneeMurphy Chemical Limited
InventorDavid John Judd
Life of this patent
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Abstract
A herbicidal composition containing a plant fertilizer component comprising a coherent extrudate containing an intimate dispersion of (A) 1 to 100 parts by weight of a plant fertilizer component; and (B) one part by weight of a herbicide component having a melting or softening point below 145.degree. C and below that of component (A) when mixed therewith said component (B) also having a solubility in water not exceeding lg/liter at 20.degree. C. whereby release of said fertilizer component from said extrudate in use thereof is retarded.
Claims11
A method of making a plant fertilizer-herbicide composition which comprises:
- a. making a dry mixture of 1 to 100 parts by weight of a plant fertilizer component (A) selected from the group consisting of urea, ammonium nitrate, ammonium sulphate, ammonium chloride, ammonium phosphate, calcium nitrate, sodium nitrate, potassium nitrate, urea-aldehyde condensates, methylene ureas and mixtures thereof with ammonium phosphate, potassium nitrate, potassium phosphate, potassium sulphate, and potassium chloride;
- and 1 part by weight of a herbicide component (B) having a melting or softening point below 145.degree. C and below that of component (A) when mixed therewith, said component (B) also having a solubility in water not exceeding 1g/liter at 20.degree. C;
- wherein said herbicide component is selected from the group consisting of 2-tert-butyl-4,6-dinitro-5-methylphenyl acetate, 2-tert-butyl-4,6-dinitro-phenyl acetate, 2-tert-butyl-4,6-dinitrophenyl ethyl fumarate, 3-(4-bromo-3-chlorophenyl)-1-methoxy-1-methylurea, 3-(4-chlorophenyl)-1-methoxy-1-methylurea, isopropyl N-phenyl-carbamate, 2-chloro-N-isopropyl-acetanilide, and a triazine herbicide of the general formula:
- ##STR3## wherein X is OR or SR, the R groups being the same or different lower alkyl groups;
- b. thereafter extruding the dry mixture through a die at a temperature of 70.degree. to 145.degree. C whereby said herbicide component acts as a lubricant to permit ready extrusion of said fertilizer component in solid form and subsequently solidifies to bind said fertilizer component into a coherent extrudate.
A method of making a plant fertilizer-herbicide composition which comprises:
- a. making a dry mixture of 1 to 100 parts by weight of a plant fertilizer component (A), said plant fertilizer component comprising urea or a mixture of urea and a phosphate or potassium salt;
- and 1 part by weight of a herbicide component (B) having a melting or softening point below 145.degree. C and below that of component (A) when mixed with said component (B) also having a solubility in water not exceeding 1g/liter;
- said herbicide selected from the group consisting of compounds of the formula:
- ##STR4## in which R is a branched butyl group;
- R.sup.1 is a hydrogen atom or a methyl group;
- and R.sup.2 is a group R.sup.3 or --CH.dbd.CH--CO.sub.2 R.sup.3, where R.sup.3 is an alkyl, alkenyl or aryl group containing 1-6 carbon atoms optionally substituted with a halogen atom, alkoxyl group, or substituted amino group;
- and a triazine herbicide of the general formula:
- ##STR5## wherein X is OR or SR, the R groups being the same or different lower alkyl groups;
- b. thereafter extruding the dry mixture through a die whereby said herbicide component acts as a lubricant to permit ready extrusion of said fertilizer component in solid form and subsequently solidifies to bind said fertilizer component into a coherent extrudate.
Dependencies are inferred from the claim text.