Aminophthalic anhydride copolymers
OwnerGaetano F. D'Alelioinventor
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Abstract
Processes are described for the preparation of substantially pure aminophthalic anhydrides and for polymerizing these monomers to unmodified and modified improved polyamic acid and polyimides.
Claims16
The process of preparing a film forming polyamic acid which comprises reacting an aminophthalic anhydride of the formula H.sub.2 NC.sub.6 H.sub.n Y.sub.3-n (CO).sub.2 O wherein Y represents a halogen selected from the group consisting of F, Br and Cl and n represents an integer having a value of 0 to 3, in an inert organic solvent in which the polymer is soluble at a temperature of about 10-100.degree. C with 0.5 to 0.001 mole per mole of anhydride of a compound having the formula Ar(NH.sub.2).sub.2 in which Ar represents single, fused or heterocyclic aromatic ring, said heterocyclic ring being selected from the class consisting of pyridine, quinoline and quinoxaline or a multiplicity of such rings linked to each other directly ##STR19## in which R represents hydrocarbon group containing one to twelve carbon atoms and the remaining positions in the Ar groups being occupied by hydrogen and a halogen selected from the class consisting of F, Cl and Br.
The film forming polyamic acid which consists of the reaction product of an aminophthalic anhydride of the formula H.sub.2 NC.sub.6 H.sub.n Y.sub.3-n (CO).sub.2 O wherein Y represents a halogen selected from the class consisting of F, Br and Cl, and n represents an integer having a value of 0 to 3, and about 0.1 to 0.001 mole of a compound having the formula Ar(NH.sub.2).sub.2 in which Ar represents single, fused or heterocyclic aromatic ring, said heterocyclic ring being selected from the class consisting of pyridine, quinoline and quinoxaline, or a multiplicity of such rings linked to each other directly or by ##STR20## linkages in which R represents hydrogen or a hydrocarbon group containing one to twelve carbon atoms, and the remaining positions in the Ar groups being occupied by hydrogen or a halogen selected from the class consisting of F, Cl and Br.
Dependencies are inferred from the claim text.