Synthetic aircraft turbine oil
AssigneeTexaco Inc.
InventorsJohn W. Nebzydoski, Edwin L. Patmore
Life of this patent
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Abstract
Synthetic lubricating oil composition comprising a major portion of an aliphatic ester base oil having lubricating properties formed from the reaction of a pentaerythritol or trimethylolpropane and an organic monocarboxylic acid containing (a) from about 0.01 to 0.5 percent of a substituted 4-aminotriazole; (b) from about 0.3 to 5 percent of an alkyl or alkaryl phenylnaphthylamine; (c) from about 0.3 to 5 percent of a dialkyldiphenylamine; and (d) from about 0.25 to 10 percent of a hydrocarbyl phosphate ester.
Claims13
A synthetic lubricating oil composition comprising a major portion of an aliphatic ester base oil having lubricating properties formed from the reaction of a pentaerythritol or trimethylolpropane and a saturated hydrocarbyl monocarboxylic acid having from about 2 to 18 carbon atoms per molecule, containing
- A. from about 0.01 to 0.5 weight percent of a substituted 4-amminotriazole represented by a formula selected from the group consisting of:
- ##STR8## d. The amine salt of (c) in which the amine is a primary monoamine represented by the formula:
- R""NH.sub.2
- in which Y is a hydrocarbylidene radical or hydroxy-substituted hydrocarbylidene radical having from 8 to 18 carbon atoms, R is hydrogen or an aliphatic hydrocarbon radical having from 1 to 4 carbon atoms R'" is an alkylene radical having from 2 to 18 carbon atoms, and R"" is an aliphatic hydrocarbon radical having from 1 to 18 carbon atoms B. From about 0.3 to 5 percent by weight of the lubricating oil composition of an alkyl or alkarylphenyl naphthylamine represented by the formula:
- ##STR9## in which R is an alkyl or alkaryl radical having from about 4 to 12 carbon atoms,
- C. from about 0.3 to 5 percent of a dialkyldiphenyamine in which the alkyl radicals have from 4 to 12 carbon atoms, and
- D. from about 0.25 to 10 percent of a trihydrocarbyl phosphate in which said hydrocarbyl radical contains an aryl ring and contains from about 6 to 18 carbon atoms.
A synthetic lubricating oil composition comprising a major portion of an aliphatic ester base oil having lubricating properties formed from the reactions of a pentaerythritol or trimethylolpropane and a saturated hydrocarbyl monocarboxylic acid having from about 2 to 18 carbon atoms per molecule, containing
- A. from about 0.01 to 0.5 weight percent of a substituted 4-aminotriazole represented by the formula:
- ##STR10## in which Y is a hydrocarbylidene radical or hydroxy-substituted hydrocarbylidene radical having from 8 to 18 carbon atoms,
- B. from about 0.3 to 5 percent by weight of the lubricating oil composition of an alkyl or alkarylphenyl naphthylamine represented by the formula:
- ##STR11## in which R is an alkyl or alkaryl radical having from about 4 to 12 carbon atoms,
- C. from about 0.3 to 5 percent of a dialkyldiphenylamine in which the alkyl radicals have from 4 to 12 carbon atoms, and
- D. from about 0.25 to 10 percent of a trihydrocarbyl phosphate in which said hydrocarbyl radical contains an aryl ring and contains from about 6 to 18 carbon atoms.
A synthetic lubricating oil composition comprising a major portion of an aliphatic ester base oil having lubricating properties formed from the reaction of a pentaerythritol or trimethylolpropane and a saturated hydrocarbyl monocarboxylic acid having from about 2 to 18 carbon atoms per molecule, containing
- A. from about 0.01 to 0.5 weight percent of a substituted 4-aminotriazole represented by the formula:
- ##STR12## in which R is hydrogen or an aliphatic hydrocarbon radical having from 1 to 4 carbon atoms,
- B. from about 0.3 to 5 percent by weight of the lubricating oil composition of an alkyl or alkarylphenyl naphthylamine represented by the formula:
- ##STR13## in which R is an alkyl or alkaryl radical having from about 4 to 12 carbon atoms,
- C. from about 0.3 to 5 percent of a dialkyldiphenyamine in which the alkyl radicals have from 4 to 12 carbon atoms, and
- D. from about 0.25 to 10 percent of a trihydrocarbyl phosphate in which said hydrocarbyl radical contains an aryl ring and contains from about 6 to 18 carbon atoms.
A synthetic lubricating oil composition comprising a major portion of an aliphatic ester base oil having lubricating properties formed from the reaction of a pentaerythritol or trimethylolpropane and a saturated hydrocarbyl monocarboxylic acid having from about 2 to 18 carbon atoms per molecule, containing
- A. from about 0.01 to 0.5 weight percent of a substituted 4-aminotriazole represented by the formula:
- ##STR14## in which R is hydrogen or an aliphatic hydrocarbon radical having from 1 to 4 carbon atoms R'" is an alkylene radical having from 2 to 18 carbon atoms,
- B. from about 0.3 to 5 percent by weight of the lubricating oil composition of an alkyl or alkarylphenyl naphthylamine represented by the formula:
- ##STR15## in which R is an alkyl or alkaryl radical having from about 4 to 12 carbon atoms,
- C. from about 0.3 to 5 percent of dialkyldiphenyamine in which the alkyl radicals have from 4 to 12 carbon atoms, and
- D. from about 0.25 to 10 percent of a trihydrocarbyl phosphate in which said hydrocarbyl radical contains an aryl ring and contains from about 6 to 18 carbon atoms.
A synthetic lubricating oil composition comprising a major portion of an aliphatic ester base oil having lubricating properties formed from the reaction of a pentaerythritol or trimethylolpropane and a saturated hydrocarbyl monocarboxylic acid having from about 2 to 18 carbon atoms per molecule, containing
- A. from about 0.01 to 0.5 weight percent of N-salicylidene-4-amino-1,2,4-triazole,
- B. from about 0.3 to 5 percent by weight of the lubricating oil composition of an alkyl or alkarylphenyl naphthylamine represented by the formula:
- ##STR16## in which R is an alkyl or alkaryl radical having from about 4 to 12 carbon atoms,
- C. from about 0.3 to 5 percent of a dialkyldiphenyamine in which the alkyl radicals have from 4 to 12 carbon atoms, and
- D. from about 0.25 to 10 percent of a trihydrocarbyl phosphate in which said hydrocarbyl radical contains an aryl ring and contains from about 6 to 18 carbon atoms.
A synthetic lubricating oil composition comprising a major portion of an aliphatic ester base oil having lubricating properties formed from the reaction of a pentaerythritol or trimethylolpropane and a saturated hydrocarbyl monocarboxylic acid having from about 2 to 18 carbon atoms per molecule, containing
- A. from about 0.01 to 0.5 weight percent of N-benzylidene-4-amino-1,2,4,-triazole,
- B. from about 0.3 to 5 percent by weight of the lubricating oil composition of an alkyl or alkarylphenyl naphthylamine represented by the formula:
- ##STR17## in which R is an alkyl or alkaryl radical having from about 4 to 12 carbon atoms,
- C. from about 0.3 to 5 percent of a dialkyldiphenylamine in which the alkyl radical have from 4 to 12 carbon atoms, and
- D. from about 0.25 to 10 percent of a trihydrocarbyl phosphate in which said hydrocarbyl radical contains an aryl ring and contains from about 6 to 18 carbon atoms.
A synthetic lubricating oil composition comprising a major portion of an aliphatic ester base oil having lubricating properties formed from the reaction of a pentaerythritol or trimethylolpropane and a saturated hydrocarbyl monocarboxylic acid having from about 2 to 18 carbon atoms per molecule, containing
- A. from about 0.01 to 0.5 weight percent of N-dodecylidene-4-amino-1,2,4-triazole,
- B. from about 0.3 to 5 percent by weight of the lubricating oil composition of an alkyl or alkarylphenyl naphthylamine represented by the formula:
- ##STR18## in which R is an alkyl or alkaryl radical having from about 4 to 12 carbon atoms,
- C. from about 0.3 to 5 percent of a dialkyldiphenyamine in which the alkyl radicals have from 4 to 12 carbon atoms, and
- D. from about 0.25 to 10 percent of a trihydrocarbyl phosphate in which said hydrocarbyl radical contains an aryl ring and contains from about 6 to 18 carbon atoms.
A synthetic lubricating oil composition consisting of 90 to 98 percent of an aliphatic ester base oil having lubricating properties formed from the reaction of a pentaerythritol or trimethylolpropane and a saturated hydrocarbyl monocarboxylic acid having from about 2 to 18 carbon atoms per molecule, containing
- A. from about 0.01 to 0.5 weight percent of a substituted 4-aminotriazole represented by a formula selected from the group consisting of:
- ##STR19## d. The amine salt of (c) in which the amine is a primary monoamine represented by the formula:
- R""NH.sub.2
- in which Y is a hydrocarbylidene radical or hydroxy-substituted hydrocarbylidene radical having from 8 to 18 carbon atoms, R is hydrogen or an aliphatic hydrocarbon radical having from 1 to 4 carbon atoms R'" is an alkylene radical having from 2 to 18 carbon atoms, and R"" is an aliphatic hydrocarbon radical having from 1 to 18 carbon atoms
- B. from about 0.3 to 5 percent by weight of the lubricating oil composition of an alkyl or alkarylphenyl naphthylamine represented by the formula:
- ##STR20## in which R is an alkyl or alkaryl radical having from about 4 to 12 carbon atoms,
- C. from about 0.3 to 5 percent of a dialkyldiphenyamine in which the alkyl radicals have from 4 to 12 carbon atoms, and
- D. from about 0.25 to 10 percent of a trihydrocarbyl phosphate in which said hydrocarbyl radical contains an aryl ring and contains from about 6 to 18 carbon atoms.
Dependencies are inferred from the claim text.