3-Indolyl-3-phenyl-phthalides
AssigneeCiba-Geigy Corporation
InventorsRobert Garner, Jean Claude Petitpierre
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AssigneeCiba-Geigy Corporation
InventorsRobert Garner, Jean Claude Petitpierre
Estimating the term…
Phthalides of the formula ##STR1## wherein R.sub.1 and R.sub.2, independently of the other, represent hydrogen, alkyl with 1 to 12 carbon atoms, alkoxyalkyl with 2 to 8 carbon atoms, cycloalkyl with 5 or 6 carbon atoms, benzyl or phenyl, X represents alkyl with 1 to 12 carbon atoms, alkoxy with 1 to 12 carbon atoms or acyloxy with 2 to 12 carbon atoms, Y represents alkyl with 2 to 12 carbon atoms, alkoxy with 3 to 12 carbon atoms or acyloxy with 2 to 12 carbon atoms, Z represents hydrogen, alkyl having 1 to 12 carbon atoms or phenyl, U represents alkyl having 3 to 12 carbon atoms, benzyl or cyanoethyl, or may also represent W when R.sub.1 and R.sub.2 both are benzyl, W represents hydrogen, methyl or ethyl and n is 1 or 2, the benzene rings A and B may be substituted by an amino group optionally substituted by alkyl with 1 to 6 carbon atoms and the benzene ring B may also be substituted by nitro or halogen. The phthalides are particularly useful as color formers which give intense blue colors when they are contacted with an electron-accepting co-reactant such as silton clay or a phenolic resin.
A phthalide compound of the formula ##STR22## wherein R.sub.1 and R.sub.2, independently of the other, represent hydrogen, alkyl with 1 to 12 carbon atoms, alkoxyalkyl with 2 to 8 carbon atoms, cycloalkyl with 5 or 6 carbon atoms, benzyl or phenyl, X represents alkyl with 1 to 12 carbon atoms, alkoxy with 1 to 12 carbon atoms or alkanoyloxy with 2 to 4 carbon atoms, Z represents hydrogen, alkyl having 1 to 12 carbon atoms or phenyl, U' represents alkyl having 7 to 12 carbon atoms, benzyl or .beta.-cyanoethyl, and A and B represent hydrogen, dimethylamino, diethylamino or n-hexylamino and B also represents nitro or halogen.
A phthalide compound of formula ##STR26## wherein R.sub.1 and R.sub.2, independently of the other, represent hydrogen, alkyl with 1 to 12 carbon atoms, alkoxyalkyl with 2 to 8 carbon atoms, cycloalkyl with 5 to 6 carbon atoms, benzyl or phenyl, Y represents alkyl having 2 to 12 carbon atoms, alkoxy having 3 to 12 carbon atoms, or alkanoyloxy with 2 to 4 carbon atoms, W' represents alkyl having 7 to 12 carbon atoms and A and B represent hydrogen, dimethylamino, diethylamino or n-hexylamino and B also represents nitro or halogen.
Dependencies are inferred from the claim text.