Flame resistant polyamide moulding compositions
AssigneeHoechst Aktiengesellschaft
InventorsWalter Herwig, Hans-Jerg Kleiner
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Abstract
The present invention relates to novel agents for the flame-proofing of polymers, especially transparent polyamides. These agents, phosphinylphosphinic acids, are used in quantities of 3 to 40 weight percent calculated on the weight of the polymer. These flame-proofing agents can easily be prepared and render the polymers flame-proof to a high degree without deteriorating the mechanical and physical properties.
Claims6
A flame-proofed polyamide molding composition containing as a flame-proofing substance at least one phosphinylphosphinic acid of the formula ##STR17## wherein R is selected from saturated open chain-, branched and cyclic alkyl radicals having from 1 to 16 carbon atoms and aryl and aralkyl radicals having from 6 to 16 carbon atoms,
- R.sub.1 is selected from alkylene groups having from 1 to 8 carbon atoms and arylene groups and n is 1 to 3.
A flame-proofed polyamide molding composition containing as a flame-proofing substance from 5 to 30% by weight, based on the weight of polyamide, of at least one phosphinylphosphinic acid of the formula ##STR18## wherein R is alkyl of 1 to 6 carbon atoms, R.sub.1 is methylene, and n is 1 to 3.
A flame-proofed transparent polyamide molding composition containing essentiall of
- A. a polyamide which is a condensation product of
- a.sub.1. 5 to 50 mol % of one or more diamines selected from 1,3-bis-(aminomethyl)-cyclohexane;
- 1,4-bis-(aminomethyl)-cyclohexane;
- 2,5-bis-(aminomethyl)-bicyclo-[2,2,1]-heptane;
- 2,6-bis(aminomethyl)-bicyclo-[2,2,1]-heptane;
- bis-(4-aminocyclohexyl) derivative of an alkane having from 1 to 6 carbon atoms;
- and m-xylylenediamine, provided that up to 50 mol % of the m-xylylenediamine may be substituted by p-xylylene diamine,
- a.sub.2. 0 to 45 mol % of one or more diamines selected from straight chain and branched aliphatic diamines containing from 4 to 20 atoms, the amino groups being separated from one another by at least 4 carbon atoms,
- b.sub.1. 5 to 50 mol % of a diacid selected from aromatic dicarboxylic acids having from 7 to 20 carbon atoms and containing carboxyl groups in meta- or para-position,
- b.sub.2. 0 to 45 mol % of a diacid selected from saturated, straight chain and branched aliphatic dicarboxylic acids having from 6 to 20 carbon atoms, the carboxyl groups of which are separated from one another by at least 4 carbon atoms and
- c. 0 to 80 mol % of at least one aliphatic aminocarboxylic acid having from 2 to 20 carbon atoms, on their lactams,
- the sum of the mol percentages of the components (a.sub.1) and (a.sub.2) equaling that of the components (b.sub.1) and (b.sub.2), the sum of the mol percentages of all components (a.sub.1), (a.sub.2), (b.sub.1), (b.sub.2) and (c) being 100,
- the sum of the percentages of the components (a.sub.1) and (b.sub.1) being in the range of from 20 to 95, the sum of the mol percentages of the components (a.sub.2), (b.sub.2) and (c) being in the range of from 5 to 80, and all mol percentages being calculated on the sum of all components (a.sub.1), (a.sub.2), (b.sub.1), (b.sub.2) and (c),
- B. from 3% to 40% by weight, based on the weight of polyamide of at least one phosphinylphosphinic acid of the formula ##STR19## wherein R is selected from saturated open chain, branched and cyclic alkyl radicals having from 1 to 16 carbon atoms and aryl and aralkyl radicals having from 6 to 16 carbon atoms,
- R.sub.1 is selected from alkylene groups having from 1 to 8 carbon atoms and arylene groups, and
- n is 1 to 3.
Dependencies are inferred from the claim text.