Preparation of ammonium and potassium zirconium carbonates
AssigneeMagnesium Elektron Limited
InventorRaymond Francis Phillips
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Abstract
Aqueous solutions of R zirconium carbonate in which R is selected from ammonium and potassium have a carbonate: zirconium molar ratio not greater than 2.05 and can impart thixotropic properties to aqueous dispersions of polymers and copolymers, such as emulsion paint. The solutions may be prepared by reacting zirconium basic carbonate with ammonium or potassium carbonate solution and have a good storage stability, especially at high concentrations. They may be stabilized further by the addition of an acid selected from tartaric and gluconic acid.
Claims5
In an aqueous solution of ammonium zirconium carbonate, the improvement wherein said solution
- a. contains 18-25% by weight of zirconium expressed as zirconium dioxide;
- b. has a molar ratio of carbonate to zirconium not greater than 2.05;
- c. is capable of imparting thixotropic properties to aqueous dispersions of polymers and copolymes when mixed therewith;
- and
- d. is stable for at least 10 hours at a temperature of 60.degree. C.
Dependencies are inferred from the claim text.