Aromatic carboxylic acid esters and amides as fixing agents
AssigneeSandoz Ltd.
InventorsHans-Peter Baumann, Hans-Georg Karmann
Life of this patent
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Abstract
The present invention relates to methods of dyeing and printing of textile materials and specifically to the use of fixing agents in such methods. In particular, the present invention relates to the use of aromatic carboxylic acid esters and amides as fixing agents in the dyeing and printing of textile materials.
Claims15
In a process wherein a fabric consisting of or containing fibers of polyester, cellulose 21/2 acetate, cellulose triacetate or polyvinyl chloride is dyed or printed, the improvement which comprises applying to the fabric before, during or after the dyeing or printing thereof a compound of the formula ##STR21## wherein X is --O-- or --NR--,
- R is hydrogen, phenyl, phenylalkyl (C.sub.7 -C.sub.22), phenyl or phenylalkyl (C.sub.7 -C.sub.22) substituted by --OH, alkyl or halogen and having up to 22 carbon atoms in the aggregate thereof, alkyl (C.sub.1 -C.sub.22), cycloalkyl (C.sub.5 -C.sub.7), alkyl (C.sub.1 -C.sub.15) cycloalkyl (C.sub.5 -C.sub.7), cycloalkyl (C.sub.5 -C.sub.7) alkyl (C.sub.1 -C.sub.15), alkyl (C.sub.1 -C.sub.15) cycloalkyl (C.sub.5 -C.sub.7) alkyl (C.sub.1 -C.sub.15) or a group --(Y.sub.2 --O).sub.m.sbsb.2 --R.sub.2
- Y.sub.1 and Y.sub.2 are, independently, ethylene, 1,2-propylene, 1,3-propylene, 1,2-butylene or phenylethylene, with the proviso that
- a. only the group Y.sub.1 or Y.sub.2 which is bound to --X--, can be 1,3-propylene, and
- b. each (Y.sub.1 -O) or (Y.sub.2 -O) chain contains no more than 2 phenylethylene groups,
- R.sub.1 and R.sub.2 are, independently, hydrogen, phenyl, phenylalkyl (C.sub.7 -C.sub.22), phenyl or phenylalkyl substituted on the phenyl nucleus by --OH, alkyl or halogen and having up to 22 carbon atoms in the aggregate thereof, alkyl (C.sub.1 -C.sub.22), cycloalkyl (C.sub.5 -C.sub.7), alkyl (C.sub.1 -C.sub.15) cycloalkyl (C.sub.5 -C.sub.7), cycloalkyl (C.sub.5 -C.sub.7) alkyl (C.sub.1 -C.sub.15), alkyl (C.sub.1 -C.sub.15) cycloalkyl (C.sub.5 -C.sub.7) alkyl (C.sub.1 -C.sub.15), or a group ##STR22## R.sub.3 is hydrogen, halogen, alkyl (C.sub.1 -C.sub.22), cycloalkyl (C.sub.5 -C.sub.7), cycloalkyl (C.sub.5 -C.sub.7) alkyl (C.sub.1 -C.sub.15), alkyl (C.sub.1 -C.sub.15) cycloalkyl (C.sub.5 -C.sub.7), alkyl (C.sub.1 -C.sub.15) cycloalkyl (C.sub.5 -C.sub.7) alkyl (C.sub.1 -C.sub.15), --CN, --COOR.sub.6, --SO.sub.3 R.sub.6, --OR.sub.6, --NHR.sub.6 or --N(R.sub.6).sub.2, --CO.sub.2 M, --SO.sub.3 M or a group --CO--X--(Y.sub.1 O).sub.m.sbsb.1 --R.sub.1,
- R.sub.4 is hydrogen, --CO.sub.2 M, --OR.sub.6 or a group --CO--X--(Y.sub.1 O).sub.m.sbsb.1 --R.sub.1,
- R.sub.5 is hydrogen, --CO.sub.2 M or a group --CO--X--(Y.sub.1 O).sub.m.sbsb.1 --R.sub.1,
- M is a charge equivalent of a cation, m.sub.1 and m.sub.2 are integers 1 to 100, the sum of all integers m.sub.1 and m.sub.2 being 1 to 100,
- and R.sub.6 is hydrogen or a group R.
Dependencies are inferred from the claim text.