Decomposition of hydroperoxides in propylene epoxidation reaction product
AssigneeShell Oil Company
InventorJames J. Coyle
Life of this patent
Estimating the term…
Abstract
In a reaction product of propylene epoxidation with an organic hydroperoxide in the presence of a heterogeneous catalyst, decomposition of residual hydroperoxides is effected by contact of the reaction product mixture at elevated temperature and pressure with a heterogeneous cobalt oxide catalyst which may also contain copper oxide as a promoter. The hydroperoxide is thereby decomposed to the corresponding alcohol without significant loss of propylene oxide or production of undesirable contaminants.
Claims6
A process for treating the reaction product of a process in which propylene is converted to propylene oxide by reaction with an organic hydroperoxide, said reaction product comprising propylene oxide and organic hydroperoxide, to decompose the organic hydroperoxide without substantial decomposition of the propylene oxide and without substantial formation of C.sub.5 to C.sub.7 hydrocarbons as products of the decomposition reaction, which comprises contacting a catalyst-free reaction mixture recovered as effluent from said epoxidation process, at a temperature in the range from about 0.degree. to about 200.degree. C and a pressure sufficient to maintain the reaction mixture in liquid phase with a non-acidic heterogeneous catalyst system consisting essentially of an oxide of cobalt on a solid support and from 0 to 100 percent by weight of copper oxide based on said cobalt oxide, and recovering a propylene oxide product essentially free of said organic hydroperoxide.
Dependencies are inferred from the claim text.