Hydrocarbon/silicon oil lubricating compositions for low temperature use
AssigneeUnion Carbide Canada Limited
InventorsWilliam Charles Morro, Leo Ernest Hakka, James Mackay Brophy, Michel Jacques Roger Hebrard, Jean Claude Courtes
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Abstract
A low temperature lubricant oil composition having improved viscosity-temperature properties, lubricating properties and pour point is described. The composition comprises a homogeneous mixture of from 1% to 50% by weight of poly(dimethylsiloxane) having an average viscosity at 100.degree. F between 100,000 cs and 1,000,000 cs, the remainder of the mixture being a hydrocarbon oil selected from certain alkenes, isoparaffins and naphthenics. The composition can also contain a foam inhibitor such as a perfluoroalkylpolyether.
Claims29
A lubricating oil composition comprising a homogeneous mixture of from 1% to 50% by weight of (A) poly(dimethylsiloxane) having the general formula:
- ##STR7##
- when R is a methyl group in essentially all cases and n has a value such that the average viscosity of the poly(dimethylsiloxane) at 100.degree. F is between 10,000 cs and 1,000,000 cs, and the remainder of said mixture consisting of (B) hydrocarbon oil having a viscosity of less than 40,000 cs at -65.degree. F, and a flashpoint higher than 175.degree. F, and said hydrocarbon oil being at least one selected from the group consisting of (a) alkenes, (b) isoparaffins, and (c) naphthenics having a single ring which has multiple alkyl substituents;
- in the case of (a) and (b), the longest carbon chain, and in the case of (c) any alkyl substituent in which the longest carbon chain exceeds five carbon atoms, has multiple substituent alkyl branches, and its methyl branched homolog has a solubility parameter of less than 7.84 and said substituent alkyl branches of four or more carbon atoms are themselves branched, and where at least 50% of said substituent alkyl branches are bonded to carbons of the longest carbon chain which are immediately adjacent, or separated by only one carbon atom.
A lubricating oil composition comprising a hydrocarbon oil, from 1% to 50% by weight of the total composition of poly(organosiloxane) and from 1 to 500 parts per million of the total composition of perfluoroalkylpolyether corresponding to the formula:
- F--[CF(CF.sub.3)CF.sub.2 O].sub.x C.sub.2 F.sub.5
- in which x has a value which provides an average molecular weight for the perfluoroalkylpolyether ranging from about 2,000 to 7,000.
Dependencies are inferred from the claim text.