Direct positive silver halide elements
AssigneeAgfa-Gevaert
InventorsWilly Joseph Vanassche, Herman Alberik Pattyn, Erik Moisar, Sieghart Klotzer
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Abstract
Direct positive silver halide emulsions are provided which contain fogged silver halide grains with a layered grain structure wherein the external shell of the silver halide grains comprise up to 20 mole % of silver iodide based on the silver halide of the shell. The emulsions show improved sensitivity and produce images of improved maximum density.
Claims23
Photographic material containing at least one direct-positive silver halide emulsion layer containing surface fogged silver halide grains selected from the group consisting of:
- a. silver halide grains that are free of internal centers promoting the deposition of photolytic silver and have adsorbed to the surface of the grains an electron-accepting compound having an anodic polarographic half-wave potential and a cathodic polarographic half-wave potential which when added together give a positive sum, and
- b. silver halide grains having a central silver halide core containing centers promoting the deposition of photolytic silver and a silver halide shell coated thereover,
- wherein the silver halide grains have been precipitated so as to form in the silver halide grains (a) or in the silver halide shell of grains (b) an external shell of silver halide containing silver iodide in an amount up to 20 mole percent based on the silver halide of the external shell sufficient to provide an emulsion having improved sensitivity and which produces images of improved maximum density, the remainder of the silver halide grains being substantially free of silver iodide.
Process for the preparation of a direct-positive silver halide emulsion comprising fogged silver halide grains having adsorbed to their surface an electron-accepting compound which comprises the steps of:
- 1. precipitating silver halide cores that are substantially free of silver iodide and free of centers promoting the deposition of photolytic silver,
- 2. precipitating on the silver halide cores a shell of silver halide containing silver iodide in an amount up to 20 mole percent based on the silver halide of the shell sufficient to provide an emulsion having improved sensitivity and which produces images of improved maximum density,
- 3. chemically fogging the silver halide grains, and
- 4. adding an electron-accepting compound having an anodic polarographic half-wave potential and a cathodic polarographic half-wave potential which when added together give a positive sum.
Process for the preparation of a direct-positive silver halide emulsion comprising fogged silver halide grains having in their interior centers promoting the deposition of photolytic silver, which comprises the steps of:
- 1. precipitating silver halide cores that are substantially free of silver iodide,
- 2. during or after formation of the silver halide cores chemically or physically treating the cores so as to form centers promoting the deposition of photolytic silver,
- 3. precipitating on the silver halide cores a shell of silver halide that is substantially free of silver iodide,
- 4. precipitating on the shell of silver halide an external shell of silver halide containing silver iodide in an amount up to 20 mole percent based on the silver halide of the external shell sufficient to provide an emulsion having improved sensitivity and which produces images of improved maximum density, and
- 5. chemically fogging the silver halide grains formed.
Dependencies are inferred from the claim text.