Process for the work-up of a contaminated inactive mercury(II)chloride/active carbon-catalyst

Abstract

Contaminated inactive mercury(II)chloride/active carbon-catalysts are worked-up. To this end the invention provides for the active carbon to be burnt with the quantity of air or oxygen or mixtures thereof necessary to produce combustion gases containing metallic mercury in vapor form together with between 0.5 and 5% by volume of oxygen and between 2 and 15% by volume of carbon monoxide; for the combustion gases to be contacted in a condensation zone with water so as to effect separation of the mercury therein; for the gases issuing from the condensation zone to be conveyed through a scrubbing zone having an alkaline liquor therein; and for the gases leaving the scrubbing zone to be delivered to the atmosphere. The apparatus for carrying out the process, which is comprised of a shaft furnace being provided in its base portion with a grate and with an ignition flap opening thereinto, and of a scrubbing tower being positioned downstream, in the direction of flow, of the furnace and receiving an alkaline liquor, is characterized in that the shaft furnace is provided in its base portion with a catalyst-supplying downpipe opening thereinto above the ignition flap; in that a condensation zone receiving water and terminating with its lower end in an outlet valve for the removal of mercury therethrough, is positioned between the shaft furnace and the scrubbing tower; and in that the upper end of the scrubbing tower terminates in a conduit running to the suction side of a fan.

Dependencies are inferred from the claim text.