Micellar dispersions with tolerance for extreme water hardness for use in petroleum recovery
AssigneeTexaco Inc.
InventorsWilliam B. Braden, Jr., Kenoth H. Flournoy
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Abstract
A novel, thickened, miscible flooding medium to displace petroleum in subterranean reservoirs is a dispersion of light hydrocarbons, water and a surfactant system. The water may have from about 1500 to 12,000 parts per million polyvalent ions such as calcium and/or magnesium. The surfactant system comprises a water soluble salt of an alkyl or an alkylaryl sulfonate plus a water soluble salt of an alkyl or alkylaryl polyethoxy sulfate anionic surfactant plus a nonionic surfactant such as a polyethoxylated alkyl phenol, a polyethoxylated aliphatic alcohol or a fatty acid mono or dialkanolamide.
Claims8
A process for recovering petroleum from a subterranean reservoir wherein a first fluid is driven through the reservoir from an injection well to a production well by a second fluid where petroleum is produced the first fluid comprising a hydrocarbon, an aqueous fluid containing from about 1500 to 12,000 parts per million ions of calcium and/or magnesium and a surfactant system wherein the surfactant system comprises
- a first anionic surfactant having one of the following general formulas:
- R -- SO.sub.3- -- Y+
- wherein R is an alkyl radical, linear or branched, having from 5 to 25 carbon atoms, and Y is a monovalent cation such as sodium, potassium or ammonium;
- or ##STR4## wherein R and Y have the same meaning as above and a second anionic surfactant having the following general formula:
- [R' --(OCH.sub.2 CH.sub.2).sub.n -- SO.sub.4]- Y+
- wherein R' is an alkyl or alkylaryl radical, linear or branched, having from 7 to 20 carbon atoms, n is an integer from 1 to 10 and Y is a monovalent cation such as sodium, potassium or ammonium and
- a nonionic surfactant having one of the following structures:
- ##STR5## wherein R" is an alkyl radical, linear or branched, having from 5 to 20 carbon atoms, A and A' are independently selected from the group consisting of hydrogen and alkanols having from 1 to 10 carbon atoms;
- or ##STR6## wherein R'" is an alkyl radical having from 5 to 20 carbon atoms, and n' is an integer from 6 to 20 or
- R"" O(CH.sub.2 CH.sub.2 O).sub.n" H
- wherein R"" is an alkyl chain having from 5 to 20 carbon atoms and n" is an integer from 6 to 20.
Dependencies are inferred from the claim text.