Treatment of ammonia synthesis purge gas

A method of synthesizing ammonia, comprising the steps of:

• i. reacting a synthesis gas comprising nitrogen and hydrogen, and also including methane, argon and helium as contaminants, at superatmospheric pressure in an ammonia synthesis reaction zone and recycling unreacted gas to the reaction zone;
• ii. withdrawing a purge gas stream at superatmospheric pressure from the gas being recycled;
• iii. removing methane and argon from the purge gas stream by cooling the purge gas stream to a sub-ambient temperature to partially condense it and form a condensate phase containing methane and argon and a hydrogen-enriched gaseous phase containing helium and separating the phases into a gaseous hydrogen-enriched stream containing helium and at least one condensate stream containing methane and argon, and recycling said gaseous hydrogen-enriched stream to said reaction zone;
• iv. providing refrigeration for said cooling and partial condensation of the purge gas stream by expanding at least a part of said at least one condensate stream and evaporating the expanded condensate in indirect heat exchange with the purge gas stream, and then withdrawing the evaporated expanded condensate as tail gas;
• v. withdrawing a single bleed stream from the recycling hydrogen enriched stream;
• vi. maintaining the concentration of methane, argon and helium in the ammonia synthesis reaction zone substantially constant by withdrawing helium, argon and methane in said bleed stream and said at least one condensate stream at substantially the same rate as they are introduced into the ammonia synthesis reaction zone with fresh synthesis gas;
• and
• vii. recovering the tail gas at a pressure above 18 psig by withdrawing said bleed stream from said hydrogen enriched stream at a temperature not exceeding 30.degree. C above said subambient temperature, expanding at least a part of said bleed stream and injecting said expanded part into said expanded condensate prior to evaporating the latter.