Process for the addition of gaseous non-halogenated olefins and acetylenes to perfluoroalkyl iodides
AssigneeCiba-Geigy Corporation
InventorMartin Knell
Life of this patent
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Abstract
Liquid perfluoroalkyl iodides are added to non-halogenated gaseous olefins or non-halogenated acetylenes in the presence of free radical generating catalysts to produce an additive reaction product essentially free of telomers. The gaseous olefin or acetylene is bubbled through liquid perfluoroalkyl iodide and catalyst at temperatures of 40.degree. to 220.degree. C and pressures no higher than atmosphere. Illustratively, ethylene is added to 1-iodoperfluoroheptane in the presence of benzoyl peroxide.
Claims14
A process for the addition of perfluoroalkyl iodides of the formula ZC.sub.n F.sub.2n I, where Z represents F or I, n is an integer of 4 - 18, said iodides are liquid at reaction temperature, to non-halogenated olefins or non-halogenated acetylenes which are gaseous at the employed reaction temperature, which comprises bubbling said olefin or acetylene into said liquid iodide, in the presence of a free-radical generating catalyst, at atmospheric or less than atmospheric pressure, at a reaction temperature of about 40.degree. C to about 220.degree. C, and recovering the reaction addition product which is essentially free of telomers.
A process for the addition of perfluoroalkyl iodides of the formula ZC.sub.n F.sub.2n I, where Z represents F or I, n is an integer of 4 - 18, said iodides are liquid at reaction temperature, to non-halgenated olefins or non-halogenated acetylenes which are gaseous at the employed reaction temperature, which comprises bubbling said olefin or acetylene into said liquid iodide, said liquid iodide containing a catalystic amount of a free-radical generating catalyst, at atmospheric or less than atmospheric pressure, at a reaction temperature of about 40.degree. to about 220.degree. C, and recovering the then formed reaction addition product which is essentially free of telomers.
The process of claiim 2 whrein Z represents I and the ratio of perfluoroalkyl iodide to said olefin or acetylene in the addition product is 1:2.
A process for making 1,1,2,2-tetrahydro-1-iodoper-fluoroheptane comprising bubbling ethylene into liquid 1-iodoper-fluoroheptane at atmospheric or less than atmospheric pressure, at a reaction temperature of about 50.degree. C to about 220.degree. C in the presence of a free-radical generating catalyst, and recovering the reaction addition product 1,1,2,2-tetrahydro-1-iodoperfluorononane, which is essentially free of telomers.
Dependencies are inferred from the claim text.