Hydrocracking process
AssigneesInstitut Francais du Petrole, BASF SE
InventorsOrtwin Reitz, Jean-Pierre Retoret
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AssigneesInstitut Francais du Petrole, BASF SE
InventorsOrtwin Reitz, Jean-Pierre Retoret
Estimating the term…
Process for hydrocracking a petroleum hydrocarbon charge contaminated with nitrogenous compounds, comprising the hydrogenation of said charge in a first reaction zone followed with a separation in two phases, gaseous and liquid, of the resulting hydrogenated product, adding to said liquid phase the effluent from a subsequent prefractionation zone, treating the resulting mixture in a second reaction zone, adding to the effluent of said second reaction zone the above-mentioned gaseous phase, treating the resulting effluent in said prefractionation zone and separating therefrom a liquid fraction, at least one portion of which is recycled to said second reaction zone and a gaseous fraction which, after cooling is separated into a gas of high hydrogen content and a liquid effluent containing products converted in at least one reaction zone, said products being separated by fractionation.
A process for hydrocracking a petroleum hydrocarbon charge contaminated with nitrogenous compounds, in which said charge is treated in a first hydrocracking reaction zone at a temperature from about 300.degree. to 550.degree. C under a pressure from about 15 to 250 atmospheres, in the presence of hydrogen and of a catalyst containing at least one hydrogenating component selected from at least one metal of the groups VI B and VIII of the periodic table of the elements, in the form of the free metal or an oxide or sulfide thereof, said hydrogenating component being deposited on a solid carrier selected from a natural or a synthesis product, said process comprising the steps of feeding the effluent from the first hydrocracking reaction zone to a first separation zone whose pressure is the same as in the first hydrocracking reaction zone and whose temperature is from 200.degree. to 300.degree. C, separating in said separation zone (a), a vapor fraction containing, ammonia and the major part of the products converted in the first hydrocracking reaction zone and (b), a liquid effluent whose ammonia content is lower than about 50 parts by weight per million of parts of said effluent, adding to said effluent at least a portion of the liquid effluent from the bottom of a prefractionation zone as hereunder defined, feeding the resulting mixture of said liquid effluent of the first separation zone and said liquid effluent from the bottom of the prefractionation zone to a second hydrocracking reaction zone where it is heated in the presence of a catalyst containing at least one hydrogenating component selected from at least one metal of the groups VI B and VIII of the periodic table of the elements, in the form of the free metal or an oxide or sulfide thereof, said hydrogenating component being deposited on a solid carrier selected from a natural or a synthesis product, at a temperature from about 300.degree. to 550.degree. C under a pressure from about 15 to 250 atmospheres, admixing the new effluent obtained from the second hydrocracking reaction zone with the vapor fraction withdrawn from the first separation zone, feeding the resulting mixture of said effluent of said second hydrocracking reaction zone with said vapor fraction to a prefractionation zone operated under the same pressure as in the hydrocracking reaction zone from where said effluent has been withdrawn, separating in said prefractionation zone, by stripping with a gas as defined below, the liquid and gaseous phases of said effluent, so as to obtain, at the top of the prefractionation zone, a gaseous fraction containing mainly hydrogen and the major portion of the products converted in at least the hydrocracking reaction zone from where said effluent issues, and, at the bottom of the prefractionation zone, a fraction of heavy or uncoverted products, at least one part of which is recycled to at least the second hydrocracking reaction zone from where said effluent has been withdrawn, said gaseous fraction, withdrawn from the top of said prefractionation zone, being fed, after cooling, to a separation zone from wherein it is recovered, a gas of high hydrogen content and a new liquid effluent which is fed to a fractionation zone in order to separate the desired cuts as final products, in which process the gas used for the stripping step contains hydrogen, the said gas comprised of, at least partly, of the said gas of high hydrogen content obtained after cooling of the said gaseous fraction withdrawn from the top of the prefractionation zone of the said gas comprised of a mixture of fresh hydrogen with at least one portion of the said gas of high hydrogen content obtained after cooling of the said gaseous fraction withdrawn from the top of the prefractionation zone.
A process according to claim 13, in which the temperature of introduction of the effluent feeding the prefractionation column, is from about 200.degree. to 380.degree. C.
A process for hydrocracking a petroleum hydrocarbon charge, contaminated with nitrogenous compounds, in which said charge is treated in a first hydrocracking reaction zone at a temperature from about 300.degree. to 470.degree. C under a pressure from about 50 to 250.degree. atmospheres, in the presence of hydrogen and of a catalyst containing at least one hydrogenating component selected from at least one metal of the groups VI B and VII of the periodic table of the elements, in the form of the free metal or an oxide or sulfide thereof, said hydrogenating component being deposited on a solid carrier selected from a natural or a synthesis product, said process comprising the steps of feeding the effluent from the first hydrocracking reaction zone to a first separation zone, whose pressure is the same as in the first hydrocracking reaction zone and whose temperature is from 250.degree. to 290.degree. C, separating in said separation zone, (a) a vapor fraction containing mainly ammonia and the major portion of the products converted in the first hydrocracking reaction zone and, (b) a liquid effluent whose ammonia content is lower than about 50 parts per million of parts of said effluent by weight, adding to said effluent at least one portion of the liquid effluent from the bottom of a prefractionation ation zone a hereunder defined, feeding the resulting mixture of said liquid effluent of the first separation zone and said liquid effluent from the bottom of the prefractionation zone to a second hydrocracking reaction zone where it is treated at a temperature from about 300.degree. to 440.degree. C, said temperature being about 30.degree. to 100.degree. C below the temperature prevailing in the first hydrocracking reaction zone, in the presence of a catalyst defined as the catalyst of the first hydrocracking reaction zone, under a pressure from about 50 to 250.degree. atmospheres, admixing the new effluent obtained at the outlet from the second hydrocracking reaction zone with the vapor fraction withdrawn from said first separation zone, feeding the resulting mixture, at a temperature from about 200.degree. to 380.degree. C, to a prefractionation zone operated under the same pressure as in the hydrocracking reaction zone from where said new effluent was withdrawn, separating in said prefractionation zone, by stripping with a gas containing at least a portion of recycle hydrogen, the liquid and gaseous phase of said mixture so as to obtain, at the top of the prefractionation zone, a gaseous fraction containing mainly hydrogen and the major portion of the products converted in at least the hydrocracking reaction zone from where is issued said new effluent, and, at the bottom of the prefractionation zone, a fraction of heavy or unconverted products, the major portion of which has an initial distillation point from about 160.degree. to 200.degree. C and at least one portion of which is recycled to the second hydrocracking reaction zone, but not to the first hydrocracking reaction zone, said gaseous fraction, withdrawn from the top of said prefractionation zone, being fed, after cooling, to a separation zone from where is recovered a gas of high hydrogen content which is at least partly recycled to the said prefractionation zone, as stripping gas, and to at least one of the two hydrocracking reaction zones and a new liquid effluent which is fed to a fractionation zone in order to obtain the cuts desired as final products, and a bottom product which is at least partially fed back with the charge to the first reaction zone.
Dependencies are inferred from the claim text.