Multiphase block and graft copolymers comprising a hydrophilic continuous phase and hydrophobic domains
AssigneeExxon Research & Engineering Co.
InventorsRobert D. Lundberg, Neville G. Thame
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AssigneeExxon Research & Engineering Co.
InventorsRobert D. Lundberg, Neville G. Thame
Estimating the term…
This invention relates to thermoplastic, multiphase copolymers selected from the group consisting of copolymers represented by graft copolymers having the general formula ##STR1## AND BLOCK COPOLYMERS HAVING THE GENERAL FORMULA XB--[AB].sub.n --yA wherein n is an integer .gtoreq.1, m is >1, x and y are 0 or 1, and y is 1 when n is 1, A is a thermoplastic, hydrophobic polymer block having a softening point (i.e., a glass transition or crystalline melting point) of at least 35.degree. C and a molecular weight of at least 2,000, and B is a thermoplastic, hydrophilic polymer block having a softening point of at least about 35.degree. C and a molecular weight of at least about 6,000, which comprises from about 30-97 wt % of said copolymer. The novel polymers of this invention are useful for making water containing gels. Preferably, the thermoplastic multiphase copolymer is a styrene-ethylene oxide copolymer. The novel polymers are made by a process which allows one to prepare a copolymer which is substantially free of homopolymeric impurities. The compositions of the instant invention are melt processable by conventional thermoplastic techniques.
A composition of matter which comprises a thermoplastic having an average molecular weight of at least 10,000 selected from the group consisting of copolymers represented by graft copolymers having the general formula ##STR8## and block copolymers having the general formula xB--[AB].sub.n --ya wherein n is an integer .gtoreq.1, m is >1, x and y are 0 or 1, and y is 1 when n is 1, A is a thermoplastic hydrophobic polymer block having a softening point of at least about 35.degree. C. and a molecular weight of at least about 2,00, A being selected from the group consisting of polystyrene, poly(t-butyl styrene), polyvinyl toluene, polymethylmethacrylate, polyamides and copolymers thereof, and B is a thermoplastic hydrophilic polymer block which comprises from about 30-97 weight % of said copolymer, B being selected from the group consisting of poly(ethylene oxide), polyacrylamide, poly- .alpha.-hydroxyethyl-methacrylate and copolymers thereof wherein the hydrophilic portion is greater than 50%, and said composition further characterized as being a water swollen gel.
Dependencies are inferred from the claim text.