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AssigneeSankyo Company, Limited
InventorsTeruomi Jojima, Hideakira Tsuji, Shinjiro Yamamoto, Teiji Omino
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New organic phosphorus compounds having the formula ##STR1## wherein R.sub.1 represents an alkyl group of 1-4 carbon atoms, R.sub.2 represents an alkoxy group of 1-4 carbon atoms or phenyl group and R.sub.3 represents hydrogen atom, an alkyl group of 1-4 carbon atoms, phenyl group or the group of the formula -X-R.sub.4 in which R.sub.4 represents an alkyl group of 1-6 carbon atoms or a benzyl group which may be substituted with a halogen atom in the phenyl moiety and X represents oxygen atom or sulfur atom. The present compounds are prepared by reacting a phosphoric or phosphonic acid halide having the formula ##STR2## wherein R.sub.1 and R.sub.2 are as defined above and Y represents a halogen atom with a pyridazinone derivative having the formula ##STR3## wherein R.sub.3 is as defined above. The present compounds show a superior insecticidal activity against various harmful insects, e.g., rice stem borers, planthoppers, mites, aphids, flies, mosquitoes and the like and thus they are useful as an insecticide or acaricide.
An insecticidal composition which comprises a carrier and as an active ingredient an effective amount of O,O-diethyl O-(6-n-propoxy-3-pyridazyl)phosphorothioate.
An insecticidal composition which comprises a carrier and as an active ingredient an effective amount of O,O-diethyl O-(6-n-pentoxy-3-pyridazyl)phosphorthioate.
An insecticidal composition which comprises a carrier and as an acitive ingredient an effective amount of O,O-diethyl O-(6-n-hexyloxy-3-pyridazyl)phosphorothioate.
An insecticidal composition which comprises a carrier and as an active ingredient an effective amount of O,O-diethyl O-(6-isobutoxy-3-pyridazyl)phosphorothioate.
An insecticidal composition which comprises a carrier and as an active ingredient an effective amount of O,O-diethyl O-[6-(3-methyl-n-butoxy)-3-pyridazyl] phosphorothioate.
An insecticidal composition which comprises a carrier and as an active ingredient an effective amount of O,O-diethyl O-(6-isopropoxy-3-pyridazyl)phosphorothioate.
An insecticidal composition which comprises a carrier and as an active ingredient an effective amount of O,O-diethyl O-(6-n-butoxy-3-pyridazyl) phosphorothioate.
An insecticidal composition which comprises a carrier and as an active ingredient an effective amount of O,O-diethyl O-(6-ethoxy-3-pyridazyl) phosphorothioate.
An insecticidal composition which comprises a carrier and as an active ingredient an effective amount of O,O-diisopropyl O-(6-ethoxy-3-pyridazyl)phosphorothioate.
An insecticidal composition which comprises a carrier and as an active ingredient an effective amount of O,O-diethyl O-(6-methylthio-3-pyridazyl)phosphorothioate.
An insecticidal composition which comprises a carrier and as an active ingredient an effective amount of O,O-diisopropyl O-(6-methylthio-3-pyridazyl)phosphorothioate.
An insecticidal composition which comprises a carrier and as an active ingredient an effective amount of O,O-di-n-butyl O-(6-methylthio-3-pyridazyl) phosphorothioate.
An insecticidal composition which comprises a carrier and as an active ingredient an effective amount of O,O-diethyl O-(6-ethylthio-3-pyridazyl)phosphorothioate.
An insecticidal composition which comprises a carrier and as an active ingredient an effective amount of O,O-diisopropyl O-(6-ethylthio-3-pyridazyl)phosphorothioate.
An insecticidal composition which comprises a carrier and as an active ingredient an effective amount of O,O-diethyl O-(6-isopropylthio-3-pyridazyl)phosphorothioate.
An insecticidal composition which comprises a carrier and as an active ingredient an effective amount of O,O-diethyl O-(6-n-butylthio-3-pyridazyl)phosphorothioate.
An insecticidal composition which comprises a carrier and as an active ingredient an effective amount of O,O-diisopropyl O-(6-n-butylthio-3-pyridazy)phosphorothioate.
An insecticidal composition which comprises a carrier and as an active ingredient an effective amount of O,O-di-n-butyl O-(6-n-butylthio-3-pyridazyl)phosphorothioate.
A method for controlling harmful insects which comprises contacting said insects with an insecticidally effective amount of O,O-diethyl O-(6-n-propoxy-3-pyridazyl) phosphorothioate.
A method for controlling harmful insects which comprises contacting said insects with an insecticidally effective amount of O,O-diethyl O-(6-n-pentoxy-3-pyridazyl) phosphorothioate.
A method for controlling harmful insects which comprises contacting said insects with an insecticidally effective amount of O,O-diethyl O-(6-n-hexyloxy-3-pyridazyl) phosphorothioate.
A method for controlling harmful insects which comprises contacting said insects with an insecticidally effective amount of O,O-diethyl O-(6-isobuotxy-3-pyridazyl) phosphorothioate.
A method for controlling harmful insects which comprises contacting said insects with an insecticidally effective amount of O,O-diethyl O-[6-(3-methyl-n-butoxy)-3-pyridazyl]-phosphorothioate.
A method for controlling harmful insects which comprises contacting said insects with an insecticidally effective amount of O,O-diethyl O-(6-isopropoxy-3-pyridazyl) phosphorothioate.
A method for controlling harmful insects which comprises contacting said insects with an insecticidally effective amount of O,O-diethyl O-(6-n-butoxy-3-pyridazyl) phosphorothioate.
A method for controlling harmful insects which comprises contacting said insects with an insecticidally effective amount of O,O-diethyl O-(6-ethoxy-3-pyridazyl) phosphorothioate.
A method for controlling harmful insects which comprises contacting said insects with an insecticidally effective amount of O,O-diisopropyl O-(6-ethoxy-3-pyridazy) phosphorothioate.
A method for controlling harmful insects which comprises contacting said insects with an insecticidally effective amount of O,O-diethyl O-(6-methylthio-3-pyridazyl) phosphorothioate.
A method for controlling harmful insects which comprises contacting said insects with an insecticidally effective amount of O,O-diisopropyl O-(6-methylthio-3-pyridazyl) phosphorothioate.
A method for controlling harmful insects which comprises contacting said insects with an insecticidally effective amount of O,O-di-n-butyl O-(6-methylthio-3-pyridazyl) phosphorothioate.
A method for controlling harmful insects which comprises contacting said insects with an insecticidally effective amount of O,O-diethyl O-(6-ethylthio-3-pyridazyl) phosphorothioate.
A method for controlling harmful insects which comprises contacting said insects with an insecticidally effective amount of O,O-diisopropyl O-(6-ethylthio-3-pyridazyl) phosphorothioate.
A method for controlling harmful insects which comprises contacting said insects with an insecticidally effective amount of O,O-diethyl O-(6-isopropylthio-3-pyridazyl) phosphorothioate.
A method for controlling harmful insects which comprises contacting said insects with an insecticidally effective amount of O,O-diethyl O-(6-n-butylthio-3-pyridazyl) phosphorothioate.
A method for controlling harmful insects which comprises contacting said insects with an insecticidally effective amount of O,O-diisopropyl O-(6-n-butylthio-3-pyridazyl) phosphorothioate.
A method for controlling harmful insects which comprises contacting said insects with an insecticidally effective amount of O,O-di-n-butyl O-(6-n-butylthio-3-pyridazyl)phosphorothioate.
A method for controlling harmful mites which comprises contacting said mites with an acaricidally effective amount of O,O-diethyl O-(6-n-propoxy-3-pyridazyl)phosphorothioate.
A method for controlling harmful mites which comprises contacting said mites with an acaricidally effective amount of O,O-diethyl O-(6-n-pentoxy-3-3-pyridazyl)phosphorothioate.
A method for controlling harmful mites which comprises contacting said mites with an acaricidally effective amount of O,O-diethyl O-(6-n-hexyloxy-3-pyridazyl) phosphorothioate.
A method for controlling harmful mites which comprises contacting said mites with an acaricidally effective amount of O,O-diethyl O-(6-isobutoxy-3-pyridazyl) phosphorothioate.
A method for controlling harmful mites which comprises contacting said mites with an acaricidally effective amount of O,O-diethyl O-[6-(3-methyl-n-butoxy)-3-pyridazyl]phosphorothioate.
A method for controlling harmful mites which comprises contacting said mites with an acaricidally effective amount of O,O-diethyl O-(6-isopropoxy-3-pyridazyl) phosphorothioate.
A method for controlling harmful mites which comprises contacting said mites with an acaricidally effective amount of O,O-diethyl O-(6-n-butoxy-3-pyridazyl)phosphorothioate.
A method for controlling harmful mites which comprises contacting said mites with an acaricidally effective amount of O,O-diethyl O-(6-ethoxy-3-pyridazyl)phosphorothioate.
A method for controlling harmful mites whcih comprises contacting said mites with an acaricidally effective amount of O,O-diethyl O-(6-methylthio-3-pyridazyl)phosphorothioate.
A method for controlling harmful mites which comprises contacting said mites with an acaricidally effective amount of O,O-diethyl O-(6-ethylthio-3-pyridazyl) phosphorothioate.
A method for controlling harmful mites which comprises contacting said mites with an acaricidally effective amount of O,O-diethyl O-(6-isopropylthio-6-pyridazyl) phosphorothioate.
A method for controlling harmful mites which comprises contacting said mites with an acaricidally effective amount of O,O-diethyl O-(6-n-butylthio-3-pyridazyl) phosophorothioate.
Dependencies are inferred from the claim text.