Process for producing synthesis gases
AssigneesMetallgesellschaft Aktiengesellschaft, Ruhrgas Aktiengesellschaft
InventorsGerhard Baron, Herbert Bierbach, Carl Hafke, Gunter Pockrandt
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AssigneesMetallgesellschaft Aktiengesellschaft, Ruhrgas Aktiengesellschaft
InventorsGerhard Baron, Herbert Bierbach, Carl Hafke, Gunter Pockrandt
Estimating the term…
In the production of a synthesis gas comprising carbon monoxide and hydrogen, by a process comprising gasifying a solid fuel under a pressure of about 5-150 bars by a treatment with oxygen and water vapor to produce a water vapor-containing raw gas at a temperature of about 350.degree.-700.degree. C, the improvement which comprises further reacting the water vapor-containing raw gas under a pressure of about 5-150 bars with oxygen in a succeeding reactor to produce an intermediate product gas which leaves the reactor at a temperature between about 800.degree. C and 1400.degree. C, cooling the intermediate product gas, and freeing the intermediate product gas from sulfur compounds. A dust fuel and/or liquid hydrocarbon can be added to the raw gas as such or after prereaction with oxygen, the addition advantageously taking place in the succeeding reactor. The reactor may contain a granular bed of a catalyst such as nickel, cobalt or chromium oxide and/or sulfide, and/or a contact material or catalyst support such as an oxide, spinel or silicate of aluminum and/or magnesium. The bed can be fluidized or otherwise mechanically moved. The resulting gas is suited for use as a starting material in a methanol, ammonia, oxo or Fischer-Tropsch synthesis.
The production of a synthesis gas comprising carbon monoxide and hydrogen, by a process comprising gasifying coal in a first reaction zone under a pressure of about 5-150 bars in counterflow to oxygen and water vapor to produce a water vapor-containing raw gas having a temperature of about 350.degree. - 700.degree. C, feeding said raw gas without cooling same, into a second reaction zone and reacting it non-catalytically with oxygen under a pressure of about 5-150 bars, said second reaction zone containing a bed of heat-resisting inert granular material having a particle size of about 3-80 mm, withdrawing from said second reaction zone an intermediate product gas having a temperature between about 800.degree. C and 1400.degree. C, cooling the intermediate product gas and freeing it from sulfur compounds.
Dependencies are inferred from the claim text.