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AssigneeGesellschaft fur Kernforschung m.b.H.
InventorsHelmut Schmieder, Reinhard Kroebel
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A method is provided for preparing aqueous, radioactive waste solutions, from reprocessing plants for spent nuclear fuel and/or breeder materials and other nuclear plants, for noncontaminating solidification and/or removal of such solutions. The total quantity of the various inorganic and organic substances in the waste solution is reduced by the destruction of nitric acid, nitrates and nitrites and the formation of a waste gas mixture which is practically free of higher nitrous oxides. To bring this about, the radioactive waste solutions are subjected to an electrolysis current at such current densities at the anode and at the cathode that in one process step the substances of the group hydrazine, hydroxylamine, oxalic acid, oxalates, tartaric acid and tartrates are oxidized at the anode and the substances of the group nitric acid, nitrates and nitrites are reduced at the cathode.
A method for preparing aqueous, radioactive waste solutions, from reprocessing plants for spent nuclear fuel and/or breeder materials and other nuclear plants, for non-contaminating solidification and/or removal of such solutions, in which the total quantity of the various inorganic and organic substances is reduced by the destruction of nitric acid, nitrates and nitrites and formation of a waste gas mixture which is practically free of higher nitrous oxides, comprising subjecting the radioactive waste solution to an electrolysis current in an electrolysis cell that does not contain a diaphragm at such current densities at the anode and at the cathode that, in one process step, the substances selected from the group consisting of hydrazine, hydroxylamine, oxalic acid, oxalates, tartaric acid and tartrates are oxidized at the anode and the substances selected from the group consisting of nitric acid, nitrates and nitrites are reduced at the cathode.
A method for preparing aqueous, radioactive waste solutions, from reprocessing plants for spent nuclear fuel and/or breeder materials and other nuclear plants, for non-contaminating solidification and/or removal of such solutions, in which the total quantity of the various inorganic and organic substances is reduced by the destruction of nitric acid, nitrates and nitrites and formation of a waste gas mixture which is practically free of higher nitrous oxides, said solution containing at least one substance selected from the group consisting of nitric acid, nitrate, and nitrite, and at least one substance selected from the group consisting of hydrazine, hydroxylamine, oxalic acid, oxalates, tartaric acid and tartrates comprising subjecting the radioactive waste solution to an electrolysis current in an electrolysis cell that does not contain a diaphragm at such current densities at the anode and at the cathode that, in one process step, those substances selected from the group consisting of hydrazine, hydroxylamine, oxalic acid, oxalates, tartaric acid and tartrates that are present are oxidized at the anode and those substances selected from the group consisting of nitric acid, nitrates and nitrites that are present are reduced at the cathode.
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