US 4,056,443 AGranted

Coke production

AssigneeCentro Sperimentale Metallurgico S.p.A.

InventorsAngelo Colletta, Luigi Palumbo

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Abstract

Coke is produced with high yield and low sulfur by heating and drying ground coking coal at 200.degree. to 300.degree. C. for 15 to 120 minutes in air, and then heating in three semicoking stages in fluidized bed reactors. The first semicoking stage is 300.degree. to 470.degree. C. for 10 to 20 minutes; the second is 400.degree. to 600.degree. C. for 10 to 20 minutes; while the third is 800.degree. to 1100.degree. C. for 10 to 20 minutes. Tar is condensed from the offgases of the first two semicoking stages and the residual gas from each is divided and 60 to 80% recycled as fluidizing gas to the same semicoking reactor. 10 to 20% of the offgases from the third semicoking stage is recycled to the third stage as fluidizing gas. In addition, oxygen is used as make-up fluidizing gas in each of the three stages, in the amount of 10 to 30 liters per kilogram of dry coal in the first stage, 5 to 20 liters per kilogram of dry coal in the second stage, and 40 to 100 liters per kilogram of dry coal in the third stage. The offgas from the third stage is high in reducing power. The condensed tar is fed to the final coke-forming operation.

A method of producing coke of low sulfur content, comprising grinding coking coal, drying and heating the ground coal at a temperature of 200.degree. to 300.degree. C. for 15 to 120 minutes by fluidizing the ground coal with gas thereby to produce a dried and heated material;

passing said material to a first semicoking stage, heating said material by fluidization in said first semicoking stage at 300.degree. l to 470.degree. C. for 10 to 20 minutes while supplying to said first semicoking stage a make-up fluidizing gas containing oxygen in a quantity of 10 to 30 normal liters per kilogram of dry coal, thereby to produce semicoke and first offgases;
cooling said first offgases to produce condensed tar and first residual gases;
recycling to said first semicoking stage as fluidizing gas 60 to 80% by volume of said first residual gases;
passing the semicoke from said first semicoking stage to a second semicoking stage, heating the semicoke in said second semicoking stage at 400.degree. to 600.degree. C. for 10 to 20 minutes while supplying to said second semicoking stage a make-up fluidizing gas containing oxygen in a quantity of 5 to 20 normal liters per kilogram of dry coal, thereby to produce semicoke and second offgases;
cooling said second offgases to produce condensed tar and second residual gases;
recycling to said second semicoking stage as fluidizing gas 60 to 80% by volume of said second residual gases;
passing the semicoke from said second semicoking stage to a third semicoking stage, heating the semicoke by fluidization in said third semicoking stage at 800.degree. to 1100.degree. C. for 10 to 20 minutes with the production of third offgases while supplying to said third semicoking stage a make-up fluidizing gas containing oxygen in a quantity of 40 to 100 normal liters per kilogram of dry coal;
recycling to said third semicoking stage as fluidizing gas 10 to 20% by volume of said third offgases;
and briquetting the semicoke from said third semicoking stage into formed coke.

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Abstract

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