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US 4,056,356 AGranted
Polyester fiber
AssigneeEastman Kodak Company
InventorsRussell Gilkey, Samuel D. Hilbert, Bobby J. Sublett, Thomas H. Wicker, Jr.
Life of this patent
Estimating the term…
Abstract
Disclosed is a textile fiber comprised of a poly(oxyethylene)-glycol modified poly(1,4-cyclohexylenedimethylene terephthalate) type polyester containing phosphorus, a stabilizer, an organic titanium compound, and optionally a manganous ion. The fiber exhibits an unobvious combination of commercially acceptable mechanical properties, commercially acceptable lightfastness, commercially acceptable gasfastness, and commercially acceptable dye rate.
Claims3
A textile fiber comprised of
- A. a polyetherester of
- 1. terephthalic acid, and
- 2. a diol component comprised of
- a. 1,4-cyclohexanedimethanol, and
- b. from 3 to 12 weight percent, based on the weight of the polyetherester, of poly(oxyethylene)glycol having a molecular weight in the range of 300-800,
- B. based on the weight of the polyetherester, from 0-150 weight parts per million of manganous ion,
- C. based on the weight of the polyetherester, from 20-500 weight parts per million phosphorus derived from
- 1. phosphorus acid,
- 2. phosphoric acid,
- 3. pyrophosphoric acid,
- 4. polyphosphoric acid, or a compound corresponding to the formula r1 ? ##STR26## where R.sup.1 is --H, a monovalent alkyl radical having 1-18 carbon atoms, a monovalent aryl or substituted aryl radical having 6-15 carbon atoms, or -O-R where R is --H, a monovalent alkyl radical having 1-18 carbon atoms or a monovalent aryl or substituted aryl radical having 6-15 carbon atoms,
- R.sup.2 is --H, monovalent alkyl radical having 1-18 carbon atoms, or a monovalent aryl or substituted aryl radical having 6-15 carbon atoms, provided that when R.sup.2 is alkyl, at least one of R.sup.2 has a chain of at least two unsubstituted methylene groups attached to the oxygen atom attached to phosphorus, ##STR27## where R.sup.1 and R.sup.2 are the same as above, ##STR28## where R.sup.4 is --H, a monovalent alkyl radical having 1-18 carbon atoms, or a monovalent aryl or substituted aryl radical having 6-15 carbon atoms,
- n = 1-6,
- R.sup.3 = (ch.sub.2).sub.x where x = 2-6, ##STR29## where R.sup.2 is the same as above,
- R.sup.5 is a divalent or tetravalent alkyl radical having 2-5 carbon atoms,
- m = 1 or 2, ##STR30## where R.sup.2 is the same as above,
- R.sup.6 is a divalent alkyl radical having 2-12 carbon atoms or a divalent aryl or substituted aryl radical having 6-15 carbon atoms, ##STR31## where R.sup.6 is the same as above,
- R.sup.7 is a divalent alkyl radical having 2-5 carbon atoms,
- D. based on the weight of the polyetherester, from 1000 to 5000 weight parts per million of a stabilizer effective to reduce oxidative degradation of the polyetherester corresponding to the structure ##STR32## where n is from 1 to 4,
- R.sup.8 is a radical selected from the group consisting of
- 1. neopentanetetrayltetrakis,
- 2. phosphinylidynetrioxy,
- 3. 2,4,6-trimethyl-1,3,5-benzenetriyltrimethylene,
- 4. alkylene having 1 to 5 carbon atoms,
- 5. alkyl having 1 to 12 carbon atoms,
- 6. 2,4,6-trioxo-1,2,3,4,5,6-hexahydro-S-triazine1,3,5-triyl)tris(3-oxotrimeth ylene),
- 7. [3-octadecyloxy)-3-oxopropyl],
- A is a monovalent radical selected from the group consisting of
- 1. tertiary alkyl having 4 to 8 carbon atoms,
- 2. alkyl having 8 to 22 carbon atoms, and
- 3. secondary alkyl having 12 to 24 carbon atoms,
- E. based on the weight of the polyetherester, from 25-200 weight parts per million titanium derived from a soluble tetravalent organic titanium compound.
29 more elements
A textile fiber comprised of
- A. a polyetherester of
- 1. terephthalic acid, and
- 2. a diol component comprised of
- a. 1,4-cyclohexanedimethanol, and
- b. from 8 to 12 weight percent, based on the weight of the polyetherester, of poly(oxyethylene)glycol having a molecular weight in the range of 400-600,
- B. based on the weight of the polyetherester, from 20-100 weight parts per million of manganous ion,
- C. based on the weight of the polyetherester, from 40-240 weight parts per million phosphorus derived from ##STR33## where R.sup.4 is --H or a monovalent alkyl radical having 1-18 carbon atoms, n = 1-6, ##STR34## where R.sup.2 is a monovalent alkyl radical having 1-18 carbon atoms,
- R.sup.5 is a tetravalent alkyl radical having 5 carbon atoms,
- D. based on the weight of the polyetherester, from 1500 to 3500 weight parts per million pentaerythritol tetrakis[3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate] having the structure ##STR35## ##STR36## where E. based on the weight of the polyetherester, from 50-150 weight parts per million titanium derived from a compound corresponding to the structure ##STR37## where R is a monovalent alkyl radical having 3-18 carbon atoms.
6 more elements
A textile fiber comprised of
- A. a polyetherester of
- 1. terephthalic acid, and
- 2. a diol component comprised of
- a. 1,4-cyclohexanedimethanol, and
- b. from 3 to 6 weight percent, based on the weight of the polyetherester, of poly(oxyethylene)-glycol having a molecular weight in the range of 400-600,
- B. based on the weight of the polyester, from 0-20 weight parts per million of manganous ion,
- C. based on the weight of the polyetherester, from 20-200 weight parts per million phosphorus derived from ##STR38## where R.sup.4 is --H or a monovalent alkyl radical having 1-18 carbon atoms,
- n = 1-6, ##STR39## where R.sup.2 is a monovalent alkyl radical having 1-18 carbon atoms,
- R.sup.5 is a tetravalent alkyl radical having 5 carbon atoms,
- D. based on the weight of the polyetherester, from 1000 to 3000 weight parts per million pentaerythritol tetrakis [3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate] having the structure ##STR40## where ##STR41## E. based on the weight of the polyetherester, from 50-150 weight parts per million titanium derived from a compound corresponding to the structure ##STR42## where R is a monovalent alkyl radical having 3-8 carbon atoms.
7 more elements
Dependencies are inferred from the claim text.