Process for the reduction of aldehydes and ketones to the corresponding carbinols
AssigneeDynapol
InventorNed M. Weinshenker
Life of this patent
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Abstract
Insoluble polymeric organotin hydrides of the formula: ##STR1## WHEREIN P represents an organic polymer backbone; R and R.sub.1 each represent a hydrogen atom, a lower alkyl group of 1 to 5 carbon atoms, an aryl group of 6 to 10 carbon atoms, or an alkaryl or aralkyl group of from 7 to 10 carbon atoms; and n is a positive number greater than 1 are disclosed. Such polymeric organotin hydrides are useful as reagents for reducing organic compounds such as organic halides, ketones, and aldehydes without the difficult problem of removing dissolved or dispersed tin impurities from the reduced compounds.
Claims2
A process of reducing a carbonyl compound selected from among aldehydes and ketones to the corresponding carbinol which comprises contacting, in liquid phase, said compound with a porous, solid, insoluble polymeric organotin hydride compound of the formula ##STR16## where P represents an organic polymer;
- R and R.sub.1 each represent hydrogen, a lower alkyl group having from 1 to 5 carbon atoms, an aryl group having from 6 to 10 carbon atoms, or an aralkyl or alkaryl group having from 7 to 10 carbon atoms;
- and n is a positive value greater than 1 at a temperature and for a period of time necessary to reduce said carbonyl compound to a reduction reaction product;
- the amount of said solid polymeric organotin hydride compound used being at least equivalent, in equivalents, to the amount of reduction to be effected;
- hydrolysing the reduction reaction product to the carbinol by contact with dilute acid and recovering the carbinol.
Dependencies are inferred from the claim text.