Refractory fiber composition and intermediate temperature range fibrous insulation composed thereof

#The invention herein relates to refractory fiber compositions. More particularly, it relates to a refractory fiber composition suitable for use in an intermediate range fibrous thermal insulation.

#Alumino-silicate fibers containing essentially no components except alumina and silica have been widely used for some years for thermal insulation capable of withstanding temperatures up to approximately 2300.degree. F (1260.degree. ); such fibers are described in U.S. Pat. No. 3,456,914. Similarly, alumino-silicate fibers containing certain added oxides, such as chromia, have been used for thermal insulation for temperatures up to approximately 2600.degree. F (1430.degree. C); such fibers are described in U.S. Pat. No. 3,449,137. Such compositions are difficult to fiberize, since the temperature range in which the melt remains in a fiberizable condition is narrow and solidification is rapid. The alumino-silicate fibers are therefore quite expensive and are used only where the high temperature ranges involved require their use.

#At the other end of the temperature scale, in the range of approximately 800.degree. F to 1200.degree. F (425.degree. C to 650.degree. ) there are a wide variety of inexpensive and readily formed fibers. Common glass fibers are ordinarily quite suitable for the temperature range of 800.degree. F to 1000.degree. F (425.degree. C to 540.degree. C). Mineral wools (which include slag wools, rock wools and the like) can normally be used at temperatures up to about 1200.degree. F (640.degree. C). The glass fibers are primarily siliceous materials, while the mineral wool materials have a substantial alumino-silicate content but also very large amounts of lime (commonly 30% to 45%) as well as magnesia (2% to 10%). The common raw materials, such as slag and various types of rock, also contain many impurities which substantially limit their maximum temperature usage. Since the principal raw material in the glass fibers is silica, it is economically feasible to use relatively pure materials for the glass fibers. However, the mineral wools cannot economically be made of pure components, such as silica, alumina, magnesia, and lime, but rather must be made of cheap materials such as slag because of cost.

#The invention herein comprises novel refractory fiber compositions which through variations in the amount of the components can be used to produce fibers suitable for thermal insulation usage at temperatures of from 1400.degree. F to 2000.degree. F (760.degree. C to 1100.degree. C). These compositions comprise by weight 84% to 97% total silica and alumina with the silicato-alumina ratio being in the range of 3:2 to 1:1, preferably approximately 5:4, and also a "dolomitic component" in a total of an amount by weight of from 3% to 16%. The dolomitic component comprises burnt dolomite or lime and magnesia, normally in generally equal amounts. The weight ratio of the silica and alumina is determined by thermal properties of the fiber and production requirements. At silica contents above 3 parts silica to 2 parts alumina, the fiber thermal properties are not satisfactory. At silica contents of less than 1 part silica to 1 part alumina, fiber production rates are unduly reduced.

#The raw materials of this composition may be any suitable source of relatively pure silica, alumina and dolomite (or separately lime and magnesia). All these materials are commercially available in a variety of forms. Physical variables such as particle size may be chosen on the basis of cost, handleability and similar considerations. Purity of the raw materials should be maintained at a relatively high level, such that no more than about 1% to 2% impurities in the form of other oxides, organic materials, and the like are present in the finished fiber, since the presence of such impurities will have detrimental effects on the temperature rating of the fiber. There are a number of materials of suitable purity commercially available.

#The fiber is formed in conventional refractory fiber forming equipment and using standard refractory fiber forming techniques. Normally production will be by electric furnace melting. The various raw materials are granulated to a size commonly used for refractory fiber melt materials, or may be purchased already so granulated. The granulated raw materials are mixed together and fed to the electric furnace where they are melted by electrical resistance melting. Melt formation may be continuous- or batch-wise melting, although the former is much preferred. The molten mixture of oxides is then fed to fiber forming devices, such as spinners or blowers. A number of types of devices for fiber formation are well known and need not be described here. The fibers so formed with have diameters on the order of 0.5 to 10 microns with the average fiber diameter being about 3.5 microns and lengths of 0.5 to 20 cm. After fiberization the fibers may be collected in bulk or passed into separate devices intended to form the fibers into mats, blankets and similar structures. The techniques heretofore commonly used to form similar articles of high temperature alumino-silcate refractory fibers are quite suitable for use with the fibers of the present invention.