Nitro-phthalides, their manufacture and their use in recording systems
AssigneeCiba-Geigy Corporation
InventorsRobert Garner, Jean Claude Petitpierre
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AssigneeCiba-Geigy Corporation
InventorsRobert Garner, Jean Claude Petitpierre
Estimating the term…
Nitro-phthalides of the formula ##STR1## in which E is a radical of the formula ##STR2## X and X' each represents alkyl with 1 to 12 carbon atoms, alkoxy with 1 to 12 carbon atoms or acyloxy with 2 to 12 carbon atoms, and X may also be hydrogen. Z represents hydrogen, alkyl having 1 to 12 carbon atoms or phenyl, Y represents hydrogen, alkyl having 1 to 12 carbon atoms, benzyl or cyanoethyl, R.sub.1, R.sub.2, R.sub.1 ' and R.sub.2 ', independently of the other, represents hydrogen, alkyl with 1 to 12 carbon atoms, alkoxyalkyl with 2 to 8 carbon atoms, cycloalkyl with 5 or 6 carbon atoms, benzyl or phenyl and the benzene ring B may be further substituted by halogen, nitro or an amino group optionally substituted by alkyl with 1 to 6 carbon atoms. The nitro-phthalides are particularly useful as color formers which give intense green, blue-green or blue colors when they are brought into contact with an electron-accepting co-reactant.
A nitro-phthalide of the formula ##STR23## wherein X.sub.1 represents alkyl with 1 to 4 carbon atoms, alkoxy with 1 to 12 carbon atoms or alkanoyloxy with 2 to 4 carbon atoms, Z.sub.1 represents hydrogen, alkyl with 1 to 4 carbon atoms or phenyl, Y.sub.1 represents hydrogen, benzyl or alkyl with 1 to 12 carbon atoms, R.sub.3 and R.sub.4 each represents hydrogen, alkyl with 1 to 12 carbon atoms or benzyl and B.sub.1 represents hydrogen, chlorine, nitro, amino, mono- or dialkylamino with 1 to 4 carbon atoms in each alkyl part and mixtures of nitro isomers thereof.
Dependencies are inferred from the claim text.