Benzofuranylphenol stabilizers
AssigneeThe B. F. Goodrich Company
InventorRobert W. Layer
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Abstract
Benzofuranylphenols are produced by (1) reacting glyoxal with a phenol in the presence of an acidic catalyst to form an acetal, and (2) thereafter partially hydrolyzing the acetal with an acidic or basic catalyst. Some benzofuranylphenols are effective stabilizers of organic materials against the deleterious effects of oxygen, heat and light. The stability of dienic polymers and styrene-acrylonitrile copolymers is particularly enhanced by incorporating stabilizing amounts of some benzofuranylphenols.
Claims21
A stabilized composition comprising (A) 100 parts by weight of at least one polymer selected from the group consisting of (1) diene polymers and (2) a polymer containing polymerized therein (a) from about 50% to about 90% by weight based upon total copolymer weight of styrene, or at least one alkyl styrene, alkoxy styrene or halostyrene, or a mixture thereof, wherein the akyl or alkoxy group contains from 1 to 8 carbon atoms, (b) from about 10% to about 50% by weight based upon total copolymer weight of at least one vinyl nitrile having the formula ##STR7## wherein R is hydrogen or an alkyl radical containing from 1 to 3 carbon atoms, and (c) from 0% to about 20% by weight of at least one monoolefin and (B) from about 0.1 part to about 10 parts by weight of at least one benzofuranylphenol having the formula ##STR8## wherein each X and Y is hydrogen, or an alkyl, alkoxyl or alkylthio group containing from 1 to 8 carbon atoms, but if any X is an alkyl, alkoxyl or alkylthio group, then at least one Y must also be an alkyl, alkoxyl or alkylthio group.
A composition of claim 6 wherein the dienic polymer is polyisoprene.
Dependencies are inferred from the claim text.