Process for producing sulfones
AssigneeKernforschungsanlage Julich Gesellschaft mit beschrankter Haftung
InventorsBertel Kastening, Dierk Knittel
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Abstract
A process for producing sulfones in which sulfur dioxide is electrolytically transformed into SO.sub.2.sup.- ions and caused to react with organic compounds having functional groups replaceable by SO.sub.2.sup.-, in an aprotic organic solvent, to produce the corresponding organosulfone. According to the present improvement, an ester such as sulfonic acid or sulfuric acid ester, is added to the solvent as an organic compound capable of reacting with halogen ions of a salt, such as tetraalkylamoniumhalogenide or tetraalkylphosphoniumhalogenide, introduced into the solvent as a conductivity-promoting agent.
Claims6
A process for producing a sulfone which comprises the steps of:
- a. introducing into the cathode compartment of an electrolysis cell subdivided into an anode compartment and a cathode compartment a reaction system comprising an aprotic organic solvent, a conductivity-promoting salt soluble in said solvent and, which salt releases halogen ions, said salt being selected from the group which consists of tetraalkylammoniumhalogenide, tetraalkylphosphoniumhalogenide, tetraarylammoniumhalogenide and tetraarylphophoniumhalogenide wherein the halogen is chlorine, bromine or iodine, sulfur dioxide, and an organic ester selected from the group consisting of a sulfonic acid ester, a sulfuric acid ester or an ester of another oxygen-containing acid capable of reacting with the halogen ions released by said salt;
- and
- b. electrolyzing said reaction system at a current density, temperature and voltage sufficient to transform said sulfur dioxide into SO.sub.2.sup.- ions and react said ester to produce the corresponding organosulfone in said cathode compartment, said organosulfone being separable from the solvent.
Dependencies are inferred from the claim text.