Purification of nickel and cobalt electroplating solutions
AssigneeThe Metalux Corporation
InventorsReuven Merker, Salvatore Lucca
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Abstract
Zinc, copper and/or iron impurities ordinarily associated with nickel or cobalt electroplating baths can be removed from solution by introducing an amount of a predetermined and selected alkylthiuram sulfide compound into the electroplating bath sufficient to convert the zinc, copper and/or iron impurities into relatively insoluble metal salts. The insoluble salts may then be removed from the bath by passing the treated solution through a standard filtering system.
Claims2
In the process wherein a metal selected from nickel and cobalt is electrodeposited from an aqueous acidic solution containing ions thereof, wherein said solution is at least periodically fed through a filtration chamber to remove impurities therefrom, and wherein, during use, metallic impurities selected from the group consisting of zinc, copper and iron build up in solution;
- the improvement in said process wherein there is added to the solution in amounts sufficient to precipitate the metallic impurities, whereby the metallic impurities are filtered out of said solution, an organic compound having the general formula a--S--X, wherein a represents the radical ##STR10## in which R is a group selected from methyl, ethyl and butyl, S is sulphur, and X is one of the following:
- --H, --Na, --K, --Li, --a as defined hereabove, --S--H, --S--S--H, --S--S--S--H, --S--Na, --S--S--Na, --S--S--S--Na, --S--K, --S--S--K, --S--S--S--K, --S--Li, --S--S--Li, --S--S--S--Li, --S--a, --S--S--a, --S--S--S--a, and --Co--S--a.
Dependencies are inferred from the claim text.