US 4,052,379 AGranted

Dyes from trifluoromethyl-2-aminobenzothiazole diazo components

AssigneeEastman Kodak Company

InventorRobert Nicholas Gourley

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Abstract

Azo dyes having the general formula: ##STR1## wherein R.sub.1 represents a substituent selected from the group consisting of hydrogen, methyl, ethyl, methoxy, ethoxy, halogen, nitro, acetyl, carbomethoxy, carboethoxy, cyano and thiocyanate, and A is an aniline, 1,2,3,4-tetrahydroquinoline or benzomorpholine coupling component, may be used as conventional disperse dyes on polyester, polyamide, acrylic, triacetate and other synthetic fabrics, and some are particularly suitable for use in the transfer printing of polyesters and polyamides.

Claims12

Dependent claims

A disperse diazo compound having the formula:

##STR31## wherein R.sup.1 is a substituent selected from the group consisting of hydrogen, methyl, ethyl, methoxy, ethoxy, halogen, nitro, acetyl, carboalkoxy, cyano, the thiocyanato, and A is a group having the formula:
##STR32## wherein R.sup.2 is hydrogen, lower alkyl, lower alkoxy, trifluoromethyl, halogen, or a group having the formula --NH-acyl;
R.sup.3 is hydrogen, lower alkyl or lower alkoxy;
R.sup.4 individually is alkyl containing one to eight carbon atoms;
cyclohexyl;
cyclohexyl substituted with lower alkyl;
or lower alkyl substituted with lower alkoxy, aryl, aryloxy, cyclohexyl, cyano, hydroxy, lower alkanoyloxy, methylsulfonyl, lower alkoxycarbonyl, lower alkoxycarbonyloxy, aroyloxy, lower alkylcarbamoyloxy, arylcarbamoyloxy, or a group having the formula:
##STR33## wherein R individually is hydrogen, lower alkyl or aryl;
R.sup.9 individually is hydrogen or lower alkyl;
R and R.sup.9 collectively are --(CH.sub.2).sub.5 -- or --CH.sub.2 CH.sub.2 OCH.sub.2 CH.sub.2 --;
R.sup.10 is hydrogen, lower alkyl, aryl or cyclohexyl;
R.sup.11 is ethylene, propylene, trimethylene, o-cyclohexylene, or o-arylene;
X is --CH.sub.2 --, --CO--, or --SO.sub.2 --;
and R.sup.12 is aryl, benzyl, cyclohexyl, 1,2,4-triazol-3-yl, or 2-benzothiazolyl;
R.sup.5 individually is hydrogen, lower alkyl, lower alkyl substituted with hydroxy, cyano, lower alkoxy, aryl, aryloxy, cyclohexyl, lower alkanoyloxy, lower alkoxycarbonyl or lower alkoxycarbonyloxy;
or aryl;
R.sup.4 and R.sup.5 in combination is a group having the formula --CH.sub.2 CH.sub.2 --Y--CH.sub.2 CH.sub.2 -- in which Y is --CH.sub.2 --, --O--, or --SO.sub.2 --;
R.sup.6 is methyl, or, when R.sup.7 and R.sup.8 each is hydrogen, R.sup.6 can be lower akyl;
R.sup.7 and R.sup.8 each is hydrogen or methyl;
each aryl moiety is phenyl or phenyl substituted with lower alkyl, lower alkoxy, lower alkoxycarbonyl, chlorine or bromine;
each acyl is formyl, lower alkanoyl, aroyl, cyclohexoyl, lower alkoxycarbonyl, lower alkylsulfonyl, carbamoyl, lower alkylcarbamoyl, or lower alkanoyl substituted with chlorine, hydroxy, aryl, cyano, lower alkoxy or aryloxy, or benzyloxy.

18 more elements

Dependencies are inferred from the claim text.

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Abstract

A disperse diazo compound having the formula:

##STR31## wherein R.sup.1 is a substituent selected from the group consisting of hydrogen, methyl, ethyl, methoxy, ethoxy, halogen, nitro, acetyl, carboalkoxy, cyano, the thiocyanato, and A is a group having the formula:
##STR32## wherein R.sup.2 is hydrogen, lower alkyl, lower alkoxy, trifluoromethyl, halogen, or a group having the formula --NH-acyl;
R.sup.3 is hydrogen, lower alkyl or lower alkoxy;
R.sup.4 individually is alkyl containing one to eight carbon atoms;
cyclohexyl;
cyclohexyl substituted with lower alkyl;
or lower alkyl substituted with lower alkoxy, aryl, aryloxy, cyclohexyl, cyano, hydroxy, lower alkanoyloxy, methylsulfonyl, lower alkoxycarbonyl, lower alkoxycarbonyloxy, aroyloxy, lower alkylcarbamoyloxy, arylcarbamoyloxy, or a group having the formula:
##STR33## wherein R individually is hydrogen, lower alkyl or aryl;
R.sup.9 individually is hydrogen or lower alkyl;
R and R.sup.9 collectively are --(CH.sub.2).sub.5 -- or --CH.sub.2 CH.sub.2 OCH.sub.2 CH.sub.2 --;
R.sup.10 is hydrogen, lower alkyl, aryl or cyclohexyl;
R.sup.11 is ethylene, propylene, trimethylene, o-cyclohexylene, or o-arylene;
X is --CH.sub.2 --, --CO--, or --SO.sub.2 --;
and R.sup.12 is aryl, benzyl, cyclohexyl, 1,2,4-triazol-3-yl, or 2-benzothiazolyl;
R.sup.5 individually is hydrogen, lower alkyl, lower alkyl substituted with hydroxy, cyano, lower alkoxy, aryl, aryloxy, cyclohexyl, lower alkanoyloxy, lower alkoxycarbonyl or lower alkoxycarbonyloxy;
or aryl;
R.sup.4 and R.sup.5 in combination is a group having the formula --CH.sub.2 CH.sub.2 --Y--CH.sub.2 CH.sub.2 -- in which Y is --CH.sub.2 --, --O--, or --SO.sub.2 --;
R.sup.6 is methyl, or, when R.sup.7 and R.sup.8 each is hydrogen, R.sup.6 can be lower akyl;
R.sup.7 and R.sup.8 each is hydrogen or methyl;
each aryl moiety is phenyl or phenyl substituted with lower alkyl, lower alkoxy, lower alkoxycarbonyl, chlorine or bromine;
each acyl is formyl, lower alkanoyl, aroyl, cyclohexoyl, lower alkoxycarbonyl, lower alkylsulfonyl, carbamoyl, lower alkylcarbamoyl, or lower alkanoyl substituted with chlorine, hydroxy, aryl, cyano, lower alkoxy or aryloxy, or benzyloxy.

18 more elements