Flame-retardant polyurethane foam compositions
AssigneeTenneco Chemicals, Inc.
InventorsBernard Rudner, Peter Daniel Pauly
Life of this patent
Estimating the term…
Abstract
Flexible, substantially nonlustrous, open-celled polyurethane foam made by an in situ process is rendered permanently flame-retardant by the incorporation of tribromoneopentyl alcohol into the reaction mixture.
Claims12
In a process for the in situ preparation of a flexible, nonlustrous, substantially membrane-free polyurethane foam from a reaction mixture comprising one or more polyols selected from the group consisting of polyester polyols and polyether polyols, an organic polyisocyanate, water, a hydrophilic organosilicon foam-stabilizing emulsifier-surfactant designed and adapted for use in the preparation of urethane polymer foam from a polyether polyol and an organic polyisocyanate, and a cell-opener selected from the group consisting of hydrophobic anti-foaming organosilicon compounds, and esters of the formula (RCOO).sub.n R', R and R' in the preceding formula being alkyl or alkenyl groups having from 1 to 30 carbon atoms, at least one of R and R' having at least 3 carbon atoms and n being an integar from one to three, with the proviso that when n is one at least one of R and R' has at least 8 carbon atoms, the amount of cell opener being from about 0.1 to about 3 parts by weight of hydrophobic anti-foaming organosilicon compound or from about 2 to about 10 parts per weight of ester of the formula (RCOO).sub.n R' per 100 parts total weight of said polyols, the improvement which comprises including in the reaction mixture a flame-retarding amount of tribromoneopentyl alcohol whereby a permanently flame-retardant open-cell foam is obtained.
A permanently flame-retardant, nonlustrous, substantially membrane-free, flexible polyurethane foam prepared in situ, which comprises the reaction product of one or more polyols selected from the group consisting of polyester polyols and polyether polyols, an organic polyisocyanate, water, a hydrophilic organo-silicon foam-stabilizing emulsifier-surfactant designed and adapted for use in the preparation of urethane polymer foam from a polyether polyol and an organic polyisocyanate, a cell-opener selected from the group consisting of hydrophobic anti-foaming organosilicon compounds, and esters of the formula (RCOO).sub.n R', R and R' in the preceding formula being alkyl or alkenyl groups having from 1 to 30 carbon atoms, at least one of R and R' having at least 3 carbon atoms and n being an integer from one to three, with the proviso that when n is one at least one of R and R' has at least 8 carbon atoms, the amount of cell opener being from about 0.1 to about 3 parts by weight of hydrophobic anit-foaming organosilicon compound or from about 2 to about 10 parts per weight of ester of the formula (RCOO).sub.n R' per 100 parts total weight of said polyols, and a flame-retarding amount of tribromoneopentyl alcohol.
Dependencies are inferred from the claim text.