Treatment of pigment
AssigneeTioxide Group Limited
InventorPeter Barry Howard
Life of this patent
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Abstract
A process for the production of the highly durable titanium dioxide pigment in which the pigment is coated with a phosphate, a silicate and a hydrous oxide of zirconium and aluminium in specified carefully controlled amounts and order of deposition.
Claims13
A process for the treatment of titanium dioxide pigment which comprises forming an aqueous dispersion of titanium dioxide containing as a dispersant 0.1% to 0.3% by weight of monoisopropanolamine, a water-soluble phosphate in an amount of 0.05% to 0.5% by weight expressed as P.sub.2 O.sub.5 or a mixture thereof, or a water-soluble silicate in an amount of 0.1% to 0.5% by weight expressed as SiO.sub.2 used alone or together with monoisopropanolamine and/or the phosphate, adding to the aqueous dispersion a water-soluble phosphate in an amount of 0.05% to 1.0% by weight expressed as P.sub.2 O.sub.5 when the dispersing agent is not solely a phosphate, a water-soluble hydrolysable acidic compound of zirconium in an amount of from 0.2% to 2.5% by weight expressed as ZrO.sub.2, a water-soluble hydrolysable acidic compound of aluminium in an amount of from 0.2% to 2.5% by weight expressed as Al.sub.2 O.sub.3, a water-soluble compound of silicon in an amount of from 0% to 1% by weight expressed as SiO.sub.2, and a water-soluble hydrolysable alkaline compound of aluminium in an amount of 0.5% to 2.5% by weight expressed as Al.sub.2 O.sub.3, and adjusting the pH of the dispersion, if necessary, to a value of pH 6.5 to 8.5 prior to recovering the treated pigment from the dispersion will all the percentages by weight being based on the weight of titanium dioxide in the aqueous dispersion.
A process for the treatment of titanium dioxide pigment prepared by the vapor phase oxidation of a titanium halide, which comprises forming an aqueous dispersion of titanium dioxide containing as a dispersant a water-soluble phosphate in an amount of 0.05% to 0.5% by weight expressed as P.sub.2 O.sub.5, adding to the aqueous dispersion a water-soluble phosphate in an amount of 0.05% to 1.0 % by weight expressed as P.sub.2 O.sub.5, a water-soluble hydrolysable acidic compound of zirconium in an amount of from 0.2% to 2.5% by weight expressed as ZrO.sub.2, a water-soluble hydroylsable acidic compound of aluminum in an amount of from 0.2% to 2.5% by weight expressed as Al.sub.2 O.sub.3, a water-soluble compound of silicon in an amount of from 0% to 1% by weight expressed as SiO.sub.2, and a water-soluble hydrolysable alkaline compound of aluminum in an amount of 0.5% to 2.5% by weight expressed as Al.sub.2 O.sub.3, and adjusting the pH of the dispersion, if necessary, to a value of pH 6.5 to 8.5 prior to recovering the treated pigment from the dispersion with all the percentages by weight being used on the weight of titanium dioxide in the aqueous dispersion.
Dependencies are inferred from the claim text.