Process for purifying polypropylene
AssigneeMontedison S.p.A.
InventorsLuciano Luciani, Gianni Nava
Life of this patent
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Abstract
Polypropylene obtained by polymerizing propylene in contact with stereospecific catalysts supported on anhydrous magnesium dihalides is purified, and the magnesium content thereof is reduced, by treating a suspension of the polypropylene in a hydrocarbon solvent with an aliphatic alcohol containing from 3 to 8 carbon atoms, followed by centrifuging to remove both the hydrocarbon solvent and the catalyst residues solubilized by the alcohol treatment.
Claims6
A process for practically completely removing magnesium dihalide from a polypropylene obtained by polymerizing propylene in contact with a catalyst prepared by mixing (A) an aluminum trialkyl partially complexed with an electron-donor compound with (B) a titanium tri- or tetra-halide supported on an anhydrous magnesium dihalide, or a complex of a titanium tri- or tetra-halide with an electron donor compound supported on an anhydrous magnesium dihalide, and which polypropylene contains catalyst residues including magnesium dihalide, said process comprising mixing an aliphatic alcohol containing from 3 to 8 carbon atoms with a suspension of the polypropylene in a hydrocarbon solvent at a temperature of from 60.degree. C to 100.degree. C to thereby solubilize catalyst residues present in the polypropylene, including the magnesium halide, and thereafter separating both the solvent and the solubilized catalyst residues including the solubilized magnesium dihalide, from the polypropylene.
Dependencies are inferred from the claim text.