Separation of bi-alkyl substituted monocyclic aromatic isomers
AssigneeUop LLC
InventorsRichard W. Neuzil, Donald J. Korous
Life of this patent
Estimating the term…
Abstract
A process for the separation of the para-isomer from a hydrocarbon feed mixture comprising at least two bi-alkyl substituted monocyclic aromatic isomers, including the para-isomer, said isomers having from 8 to about 18 carbon atoms per molecule, which process employs an adsorbent comprising a X or a Y zeolite containing selected cations at exchangeable cationic sites to preferentially adsorb the para-isomer. The para-isomer thereafter is removed from the adsorbent by contacting it with a desorbent material and is recovered as a product stream. In a preferred embodiment the process uses a simulated-moving-bed counter-current flow system.
Claims16
A process for separating the para-isomer from a feed stream comprising at least two bi-alkyl monosubstituted aromatic isomers, including the para-isomer, said isomers having more than eight and less than about eighteen carbon atoms per molecule which process employs an adsorbent comprising a X or a Y zeolite containing at exchangeable cationic sites a cation pair selected from the group consisting of barium and potassium, potassium and beryllium, potassium and magnesium, rubidium and barium, cesium and barium, potassium and rubidium and potassium and cesium and which process comprises the steps of:
- a. maintaining net fluid flow through a column of said adsorbent in a single direction, which column contains at least three zones having separate operational functions occurring therein and being serially interconnected with terminal zones of said column connected to provide a continuous connection of said zones;
- b. maintaining an adsorption zone in said column, said zone defined by the adsorbent located between a feed input stream at an upstream boundary of said zone and a raffinate output stream at a downstream boundary of said zone;
- c. maintaining a purification zone immediately upstream from said adsorption zone, said purification zone defined by the adsorbent located between an extract output stream at an upstream boundary of said purification zone and said feed input stream at a downstream boundary of said purification zone;
- d. maintaining a desorption zone immediately upstream from said purification zone, said desorption zone defined by the adsorbent located between a desorbent input stream at an upstream boundary of said zone and said extract output stream at a downstream boundary of said zone;
- e. passing said feed stream into said adsorption zone at adsorption conditions to effect the selective adsorption of said para-isomer by said adsorbent in said adsorption zone and withdrawing a raffinate output stream from said adsorption zone;
- f. passing a desorbent material into said desorption zone at desorption conditions to effect the displacement of said para-isomer from the adsorbent in said desorption zone;
- g. withdrawing an extract stream comprising said para-isomer and desorbent material from said desorption zone;
- h. passing at least a portion of said extract output stream to a separation means and therein separating at separation conditions at least a portion of said desorbent material to produce a para-isomer product;
- and
- i. periodically advancing through said column of adsorbent in a downstream direction with respect to fluid flow in said adsorption zone the feed input stream, raffinate output stream, desorbent input stream, and extract output stream to effect the shifting of zones through said adsorbent and the production of extract output and raffinate output streams.
A process for separating the para-isomer from a feed stream comprising at least two bi-alkyl monosubstituted aromatic isomers, including the para-isomer, said isomers having more than eight and less than about eighteen carbon atoms per molecule which process employs an adsorbent comprising a X zeolite containing barium and potassium at exchangeable cationic sites and which process comprises the steps of:
- a. maintaining net fluid flow through a column of said adsorbent in a single direction, which column contains at least four zones having separate operational functions occurring therein and being serially interconnected with the terminal zones of said column connected to provide a continuous connection of said zones;
- b. maintaining an adsorption zone in said column, said zone defined by the adsorbent located between a feed input stream at an upstream boundary of said zone and a raffinate output stream at a downstream boundary of said zone;
- c. maintaining a purification zone immediately upstream from said adsorption zone, said purification zone defined by the adsorbent located between an extract output stream at an upstream boundary of said purification zone and said feed input stream at a downstream boundary of said purification zone;
- d. maintaining a desorption zone immediately upstream from said purification zone, said desorption zone defined by the adsorbent located between a desorbent input stream at an upstream boundary of said zone and said extract output stream at a downstream boundary of said zone;
- e. maintaining a buffer zone immediately upstream from said desorption zone, said buffer zone defined as the adsorbent located between the desorbent input stream at a downstream boundary of said buffer zone and a raffinate output stream at an upstream boundary of said buffer zone;
- f. passing said feed stream into said adsorption zone at adsorption conditions to effect the selective adsorption of said para-isomer by said adsorbent in said adsorption zone and withdrawing a raffinate output stream comprising a bi-alkyl monosubstituted aromatic isomer and a hereinafter described desorbent material from said adsorption zone;
- g. passing a desorbent material comprising toluene into said desorption zone at desorption conditions to effect the displacement of said para-isomer from the adsorbent in said desorption zone;
- h. withdrawing an extract stream comprising said para-isomer and desorbent material from said desorption zone;
- i. passing at least a portion of said extract output stream to a first separation means and therein separating at first separation conditions at least a portion of said desorbent material to produce a para-isomer product;
- j. passing at least a portion of said raffinate output stream to a second separation means and therein separating at second separation conditions at least a portion of said desorbent material to produce a raffinate product;
- and
- k. periodically advancing through said column of adsorbent in a downstream direction with respect to fluid flow in said adsorption zone the feed input stream, raffinate output stream, desorbent input stream, and extract output stream to effect the shifting of zones through said adsorbent and the continuous production of extract output and raffinate output streams.
Dependencies are inferred from the claim text.