US 4,051,166 A · Araliphatic diisocyanates

Abstract

Novel araliphatic diisocyanates having the formula OCN(CH.sub.2).sub.3 OArX(CH.sub.2).sub.3 NCO are disclosed wherein X is oxygen or a single bond and Ar is an arylene radical. The araliphatic diisocyanates are prepared from well known and readily obtainable starting materials. When X represents a single bond, the starting material is a monohydric phenol wherein a C-alkylation reaction followed by an O-alkylation reaction with acrylonitrile provides an intermediate dipropionitrile which is converted to the diisocyanate via phosgenation of the corresponding diamine. When X represents oxygen, the starting material is a dihydric phenol wherein O-alkylation with acrylonitrile provides the dipropionitrile which in turn is converted to the diisocyanate via the phosgenation of the corresponding diamine. The diisocyanates find particular utility in the preparation of color and light stable polyurethane products.

Claims9

Dependent claims

An araliphatic diisocyanate having the formula

OCN(CH.sub.2).sub.3 OArX(CH.sub.2).sub.3 NCO
wherein X is oxygen or a single bond and Ar is an arylene radical selected from the group consisting of phenylene, tolylene, naphthylene, diphenylylene, and radicals having the formula ##STR10## wherein R.sub.1 and R.sub.2 each represent a moiety selected from the class consisting of hydrogen and alkyl having from 1 to 4 carbon atoms inclusive, and Y is selected from the group consisting of hydrogen, alkyl from 1 to 4 carbon atoms, and alkoxy from 1 to 4 carbon atoms.

Dependencies are inferred from the claim text.

Araliphatic diisocyanates

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Araliphatic diisocyanates

Life of this patent

Abstract

Claims9