Monomeric emulsion stabilizers derived from alkyl/alkenyl succinic anhydride
AssigneeThe Kendall Company
InventorsCarlos M. Samour, Mildred C. Richards
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Abstract
Quaternary ammonium salts having a lipophilic group covalently linked to the quaternary nitrogen through hydroxysuccinyloxy or hydroxysuccinylamino radicals are disclosed. These quaternary ammonium salts are useful as monomeric emulsion stabilizers.
Claims7
A compound having the formula ##STR8## wherein Z is an ethylenically unsaturated radical selected from the group consisting of acryloyloxy, methacryloyloxy, acrylamido, methacrylamido, vinyloxy, allyloxy, methallyloxy, vinylacetoxy, allylacetoxy, methallylacetoxy, 4-hydroxymaleoyloxy, 4-hydroxyfumaroyloxy, 4-hydroxymaleoylamino, 4-hydroxyfumaroylamino, 4-hydroxycitraconyloxy, 4-hydroxycitraconylamino, 4-hydroxyitaconyloxy or 4-hydroxyitaconylamino;
- R' and R" are independently selected from the group of ethylene, propylene, isopropylene, 2-hydroxypropylene, acetoxypropylene or --O--CH.sub.2 --CHR.sub.4 (O--CH.sub.2 --CHR.sub.4).sub.n where n is zero to 4;
- a = 0 or 1, and R.sub.4 is hydrogen or methyl with the proviso that a is zero where Z is vinylacetoxy, allylacetoxy, or methallylacetoxy and a is 1 otherwise;
- R.sub.1 and R.sub.2 are independently selected from the group consisting of alkyl having 1 to 7 carbon atoms, hydroxyalkyl having 1 to 7 carbon atoms, benzyl, R.sub.5 --O--CO--CH.sub.2 -- and R.sub.5 --NH--CO--CH.sub.2 -- where R.sub.5 is hydrogen or alkyl having 1 to 4 carbon atoms;
- R.sub.3 is lipophilic aliphatic hydrocarbon group having from about 7 to about 28 carbon atoms;
- and
- X.sup.- is halide, alkyl sulfate wherein the alkyl moiety has 1 to 4 carbon atoms, or toluene sulfonate.
Dependencies are inferred from the claim text.