Curable compositions diallyl esters of dicarboxylic acids and fluoropolymers
AssigneeInternational Telephone and Telegraph Corporation
InventorsElihu J. Aronoff, Kewal Singh Dhami
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Abstract
Diallyl esters of dicarboxylic acids are provided corresponding to the formula: ##STR1## wherein R is an organic radical containing from 4 to 20 carbon atoms and is selected from the group consisting of alkyl radicals, cycloalkyl radicals, mixed alkyl-cycloalkyl radicals and aralkyl radicals; R' and R" are independently selected from hydrogen, alkyl, cycloalkyl, aralkyl and aryl radicals and mixtures thereof; and the total carbon atoms in R, R' and R" is from 10 to 34. These diallyl esters are crosslinking coreactants for polymeric compositions and especially high temperature processing fluorocarbon polymers. The crosslinked compositions are particularly useful for insulation coatings.
Claims4
A high temperature processing fluorocarbon homopolymer or copolymer selected from the group consisting of polymers and copolymers of ethylene-tetrafluoroethylene, ethylene-chlorotrifluoroethylene, vinylidene fluoride, tetrafluoroethylene-vinylidene fluoride, tetrafluoroethylene-hexafluoropropylene, vinylidene fluoride-hexafluoropropylene, vinylidene fluoride-hexafluoropropylene-tetrafluoroethylene and mixtures thereof having incorporated therein a crosslinking coreactant compound comprising a diallyl ester having the structural formula:
- ##STR5## wherein R is an organic radical containing from 4 to 20 carbon atoms and is selected from the group consisting of alkyl radicals, cycloalkyl radicals and mixed alkyl-cycloalkyl radicals;
- R' and R" are independently selected from hydrogen, alkyl, cycloalkyl, aralkyl and aryl radicals and mixtures thereof;
- and the total carbon atoms in R, R' and R" is from 10 to 34.
An irradiation crosslinked high temperature processing fluorocarbon homopolymer or copolymer selected from the group consisting of polymers and copolymers of ethylene-tetrafluoroethylene, ethylene-chlorotrifluoroethylene, vinylidene fluoride, tetrafluoroethylene vinylidene fluoride, tetrafluoroethylene-hexafluoropropylene, vinylidene fluoride-hexafluoropropylene, vinylidene fluoride-hexafluoropropylene-tetrafluoroethylene and mixtures thereof containing a diallyl ester having the structural formula:
- ##STR6## wherein R is an organic radical containing from 4 to 20 carbon atoms and is selected from the group consisting of alkyl radicals, cycloalkyl radicals and mixed alkyl-cycloalkyl radicals;
- R' and R" are independently selected from hydrogen, alkyl, cycloalkyl, aralkyl and aryl radicals and mixtures thereof;
- and the total carbon atoms in R, R' and R" is from 10 to 34.
Dependencies are inferred from the claim text.