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US 4,049,863 AGranted
Fluoropolymer primer having improved scratch resistance
AssigneeE. I. Du Pont de Nemours and Company
InventorEustathios Vassiliou
Life of this patent
Estimating the term…
Abstract
Compositions containing A. fluoropolymer, B. colloidal silica, C. the salt of a polyamide acid, D. a coalescing agent, E. mica particles, mica particles coated with pigment, or metal flake, And F. a liquid carrier Are useful for priming metal, especially cookware, before topcoating it with a fluoropolymer enamel.
Claims23
A coating composition comprising
- a. about 10%-90%, by weight of the total of (a) and (b) solids, of a particulate polymer of monoethylenically unsaturated hydrocarbon monomers completely substituted with fluorine atoms or a combination of fluorine atoms and chlorine atoms, the polymer having a number average molecular weight of at least 20,000;
- b. about 10%-90%, by weight of the total of (a) and (b) solids, of a binder which comprises
- 1. about 5%-95%, by weight of the total of (1) and (2), of a colloidal silica which air-dries to form a continuous film when laid down by itself,
- and
- 2. about 5%-95%, by weight of the total of (1) and (2), of a salt of a polyamide acid represented by the structure ##STR3## where G is a hydrogen or a carboxyl group;
- .fwdarw. denotes isomerism;
- R is a tetravalent organic radical containing at least two carbon atoms, no more than two carbonyl groups of each polyamide acid unit being attached to any carbon atom of said tetravalent radical;
- R.sub.1 is a divalent radical containing at least two carbon atoms, the amide groups of adjacent polyamide acid units each being attached to separate atoms of said divalent radical;
- and
- n is a number large enough to give the polyamide acid an inherent viscosity of at least 0.1, measured as a 0.5% solution in N,N-dimethylacetamide at 30.degree. C.,
- neutralized with a stoichiometric amount of a tertiary amine;
- c. about 10-90%, by weight of (b) (2), of N-methyl pyrrolidone, dimethylformamide, dimethylacetamide, dimethylsulfoxide, cresylic acid, sulfolane or formamide;
- d. about 0.2-20%, by weight of the total of (a), (b) (1), (b) (2), (c), and (d), of mica particles, mica particles coated with pigment, or metal flake;
- and
- e. a liquid carrier.
12 more elements
Dependencies are inferred from the claim text.