Dehydration of .alpha.-methylbenzyl alcohols to form monovinylidene aromatic monomers
AssigneeThe Dow Chemical Company
InventorsJunior J. Lamson, Richard H. Hall, Edward Stroiwas, Larry D. Yats
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Abstract
.alpha.-Alkylbenzyl alcohol and substituted .alpha.-alkylbenzyl alcohols are converted in high yield and purity to styrene and substituted styrenes by contacting the alcohol in vapor phase with silica gel and steam.
Claims12
A process for preparing an ar-(t-alkyl)styrene by dehydrating an .alpha.-alkylbenzyl alcohol represented by the general formula ##STR2## wherein each R is independently hydrogen, alkyl having from 1 to 12 carbon atoms or halogen provided that an R group is t-alkyl and R.sub.1 is hydrogen or alkyl having 1 to 4 carbon atoms which method comprises a dehydration step of contacting the .alpha.-alkylbenzyl alcohol in vapor phase with a silica gel dehydration catalyst consisting essentially of silica gel in the presence of from about 0.03 to about 25 parts by weight of added water per part by weight of alcohol, said dehydration step being carried out at temperatures above 260.degree. up to about 510.degree. C., and subsequent simple distillation step of distilling the dehydration product to obtain the ar-(t-alkyl)styrene in purity greater than about 99 mole percent and containing less than 0.02 mole percent of diolefinic impurity.
A continuous process for preparing ar-(t-alkyl)styrene which comprises (1) passing a vapor phase of an ar-(t-alkyl)-.alpha.-methylbenzyl alcohol and from about 0.5 to about 20 parts by weight of water in the form of superheated steam per part of the alcohol through a column containing a heat transfer agent and a silica gel dehydration catalyst consisting essentially of silica gel in the form of a divided solid having a surface area of at least 300 square meters per gram, said process being carried out at a dehydration temperature from about 260.degree. to about 425.degree. C. such that the alcohol is dehydrated, and (2) recovering by simple distillation the resulting dehydration product in the form of ar-(t-alkyl)styrene of purity greater than about 99 mole percent and containing less than 0.02 mole percent of diolefinic impurity.
Dependencies are inferred from the claim text.