Esters and amides of trisubstituted hydroxyphenylalkanoic acids
AssigneeCiba-Geigy Corporation
InventorJohn D. Spivack
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Abstract
The compounds are esters and amides of trialkylhydroxyphenylalkanoic acid having the formula ##STR1## wherein R, R.sup.1 and R.sup.2 are independently lower alkyl or cycloalkyl groups, R.sup.3 is hydrogen, alkyl, cycloalkyl, alkylene, phenyl, phenyl substituted by alkyl groups, alkylthioethyl, thiobis-alkylene, alkyleneoxyalkylene, polyoxyalkylene or a polyvalent cyclic or acyclic hydrocarbon radical, R.sup.4 is hydrogen, lower alkyl, cycloalkyl, R.sup.5 is hydrogen, alkyl, phenyl, phenyl substituted with alkyl groups, alkylene, polyoxyalkylene or polyvalent cyclic or acyclic hydrocarbon radical, A is lower alkylene, m is 1 to 4 and n is 1 to 6. The compounds are useful as stabilizers for organic materials, especially polyolefins, which deteriorate upon exposure to light and heat.
Claims18
A compound having the formula ##STR37## wherein R is a branched alkyl of 3 to 8 carbon atoms,
- R.sup.1 and R.sup.2 are alkyl of 1 to 3 carbon atoms,
- R.sup.4 is hydrogen or alkyl of 1 to 4 carbon atoms,
- R.sup.5 is, when m is 1, alkyl of 1 to 18 carbon atoms, or when m is 2, alkylene of 2 to 12 carbon atoms or 3,6-dioxa-1,8-octamethylene,
- A is a straight chain alkylene of 1 to 3 carbon atoms, and
- m is an integer of 1 to 2.
Dependencies are inferred from the claim text.