Phenyl-azo-naphthyl dyes having a 2-acyloxy, alkoxy or hydroxy-1-arylethylamino group in the 4-position of the naphthalene ring
AssigneeSandoz Ltd.
InventorsWolfgang Groebke, Klaus Korte
Life of this patent
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AssigneeSandoz Ltd.
InventorsWolfgang Groebke, Klaus Korte
Estimating the term…
Compounds of the formula, ##STR1## in which R.sub.1 and R.sub.3, which may be the same or different, each signifies hydrogen, hydroxyl, chlorine, bromine, alkyl(C.sub.1-4), alkoxy(C.sub.1-4), alkyl(C.sub.1-4)-carbonyl, alkoxy(C.sub.1-4)-carbonyl, alkyl(C.sub.1-4)-carbonylamino or alkoxy(C.sub.1-4)-carbonylamino, R.sub.2 signifies hydrogen; alkyl(C.sub.1-4)-carbonyl; alkoxy(C.sub.1-4)-carbonyl; benzoyl; unsubstituted alkyl(C.sub.1-4); or alkyl(C.sub.1-4) monosubstituted by alkoxy(C.sub.1-4), phenoxy, benzyloxy, halo or hydroxy, R.sub.4 signifies nitro or cyano, and R.sub.5 signifies chlorine or bromine, their production and use as disperse dyes for substrates comprising high molecular weight hydrophobic polymers such as polyesters, cellulose acetates and synthetic polyamides. The dyeings exhibit good fastness to light, heat treatments, wet treatments, solvents, lubricants, rubbing, cross-dyeing, ozone, flue gas and chlorine.
A compound of the formula ##STR13## wherein each of R.sub.1 and R.sub.3 is independently hydrogen, hydroxy, chloro, bromo, C.sub.1-4 alkyl, C.sub.1-4 alkoxy, (C.sub.1-4 alkyl)- carbonyl, (C.sub.1-4 alkoxy)carbonyl, (C.sub.1-4 alkyl)- carbonylamino or (C.sub.1-4 alkoxy)carbonylamino,
A dye obtained by coupling a diazotized derivative of an amine of the formula ##STR25## with the product of the reaction of a compound of the formula ##STR26## with a compound of the formula ##STR27## optionally after etherification with a C.sub.1-4 alkyl or C.sub.1-4 alkyl monosubstituted by C.sub.1-4 alkoxy, phenoxy, benzyloxy, halo or hydroxy group-introducing agent, and, after said coupling, optionally converting any remaining hydroxy group produced by cleavage of the oxygen-containing ring into a (C.sub.1-4 alkyl)- carbonyloxy, (C.sub.1-4 alkoxy)carbonyloxy or benzoyloxy group, wherein each of R.sub.1 and R.sub.3 is independently hydrogen, hydroxy, chloro, bromo, C.sub.1-4 alkyl, C.sub.1-4 alkoxy, (C.sub.1-4 alkyl)- carbonyl, (C.sub.1-4 alkoxy)carbonyl, (C.sub.1-4 alkyl)- carbonylamino or (C.sub.1-4 alkoxy)carbonylamino,
Dependencies are inferred from the claim text.