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US 4,049,635 AGranted
Production of tetramethylene terephthalate polymers using 225.degree. to 248.degree. C. polycondensation temperature
AssigneePhillips Petroleum Company
InventorJames W. Cleary
Life of this patent
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Abstract
1,4-Butanediol and a dialkyl benzenedicarboxylate such as dimethyl terephthalate are subjected to transesterification conditions and thereafter to polycondensation in the presence of a tetraalkyl titanate catalyst at a temperature within the range of 225.degree. to 248.degree. C.
Claims8
A process for preparing a polyester comprising;
- transesterifying 1,4-butanediol and at least one dialkyl benzenedicarboxylate consisting of 80 to 100 mole percent of at least one dialkyl terephthalate and 0- 20 mole percent of at least one ester selected from dialkyl phthalates and dialkyl isophthalates, each of said alkyls of said dialkyl benzenedicarboxylate being selected from alkyl groups having 1 to 4 carbon atoms, by contacting said 1,4-butanediol and said at least one dialkyl benzenedicarboxylate with a transesterification and polycondensation catalyst consisting essentially of a tetraalkyl titanate of the formula Ti(OR).sub.4 wherein R is an alkyl group having 1 to 6 carbon atoms, said contacting being carried out at a temperature within a range of 130.degree. C. to 248.degree. C. at substantially atmospheric pressure;
- and thereafter subjecting the resulting mixture in a melt state to a temperature within the range of 225.degree. to 248.degree. C. and reduced pressure for a time within the range of 2 to 8 hours to effect polycondensation, said temperature during said polycondensation at no time exceeding 248.degree. C.
Dependencies are inferred from the claim text.