Solution polycondensation method
AssigneeHooker Chemicals & Plastics Corporation
InventorsJoseph A. Pawlak, Anthony L. Lemper, Victor A. Pattison
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Abstract
High molecular weight, linear aromatic polyesters are produced in an improved solution polycondensation process in which the hydroxyl component is added to the acid halide.
Claims8
In the solution polymerization process for the preparation of linear aromatic polyesters by reacting an organic diacid halide with a hydroxyl containing component in the presence of a catalyst, the improvement which comprises adding a hydroxyl-containing component comprising a mixture of a bisphenol and a glycol, to the diacid halide wherein the diacid halide is terephthaloyl chloride, isophthaloyl chloride or a mixture thereof, and wherein the hydroxyl-containing component is 15-85 mol percent of a glycol of 2-20 carbon atoms and a bisphenol of the formula ##STR4## in which Ar is aromatic, each T is independently selected from the group consisting of halogen, G or OG, each G is independently selected from the group consisting of alkyl, aryl, haloaryl, haloalkylaryl, alkylaryl, cycloalkyl, halocycloalkyl, and haloalkyl, E is a bivalent alkylene, haloalkylene, cycloalkylene, halocycloalkylene, arylene, haloarylene, --O--, --S--, --SO--, --SO.sub.2 --, --SO.sub.3 --, --CO--, ##STR5## or GN<, m is 0 to the number of replaceable hydrogen atoms on E, each b is 0 to the number of replaceable hydrogen atoms on Ar, and d is 0 or 1.
Dependencies are inferred from the claim text.