Electrodes for electrochemical processes
AssigneeSolvay & Cie
InventorsLucien Clerbois, Louis Degueldre, Christian Biver, Albert Degols, Yves Gobillon
Life of this patent
Estimating the term…
Abstract
A coating composition for application to an electrically conductive and relatively inert support at least the surface layer of which is titanium or a titanium alloy, to form a coated electrode for electrochemical processes, the composition essentially containing thermally decomposable compounds of iridium and of at least one non noble element selected from the group consisting of lithium, boron, beryllium, magnesium, gallium and germanium, in a liquid vehicle, the atomic ratio of iridium/non noble element being between 1/4 and 8/1. An electrode provided with a coating of this composition exhibits, inter alia, increased service life.
Claims12
In an electrode for electrochemical processes having an electrically conductive and relatively inert support at least the surface layer of which is of titanium or a titanium alloy, and an at least partial coating for said support, said coating being a protective and electrocatalytic layer obtained by heating on said support, in an oxidizing atmosphere at a temperature between 350.degree. and 800.degree. C., a coating composition consisting essentially of at least one thermally decomposable compound of iridium in a liquid vehicle, said iridium compound decomposing during the heating of the coating composition to provide said iridium in a metallic and/or oxide state, and at least one thermally decomposable compound of a non noble element selected from the group consisting of lithium, boron, beryllium and gallium in an atomic ratio iridium/non noble element of 1/4 to 8/1, said thermally decomposable compound of the non noble element decomposing during the heating of the coating composition to an oxide of the non noble element.
In an electrode for electrochemical processes having an electrically conductive and relatively inert support at least the surface layer of which is of titanium or a titanium alloy, and an at least partial coating for said support, said coating being a protective and electrocatalytic layer obtained by heating on said support, in an oxidizing atmosphere at a temperature between 350.degree. and 800.degree. C., a coating composition consisting essentially of at least one thermally decomposable compound of iridium in a liquid vehicle, said iridium compound decomposing during the heating of the coating composition to provide said iridium in a metallic and/or oxide state, and at least one thermally decomposable compound of lithium, in an atomic ratio iridium/lithium of 1/4 to 8/1, said thermally decomposable compound of lithium decomposing during the heating of the coating composition to an oxide of lithium.
In an electrode for electrochemical processes having an electrically conductive and relatively inert support at least the surface layer of which is of titanium or a titanium alloy, and an at least partial coating for said support, said coating being a protective and electrocatalytic layer obtained by heating on said support, in an oxidizing atmosphere at a temperature between 350.degree. and 800.degree. C., a coating composition consisting essentially of at least one thermally decomposable compound of iridium in a liquid vehicle, said iridium compound decomposing during the heating of the coating composition to provide said iridium in a metallic and/or oxide state, and at least one thermally decomposable compound of a non noble element selected from the group consisting of lithium and boron, in an atomic ratio iridium/non noble element of 1/4 to 8/1, said thermally decomposable compound of the non noble element decomposing during the heating of the coating composition to an oxide of the non noble element.
In an electrode for electrochemical processes having an electrically conductive and relatively inert support at least the surface layer of which is of titanium or a titanium alloy, and an at least partial coating for said support, said coating being a protective and electrocatalytic layer obtained by heating on said support, in an oxidizing atmosphere at a temperature between 350.degree. and 800.degree. C., a coating composition consisting essentially of at least one thermally decomposable compound of iridium in a liquid vehicle, said iridium compound decomposing during the heating of the coating composition to provide said iridium in a metallic and/or oxide state, and at least one thermally decomposable compound of beryllium, in an atomic ratio iridium/beryllium of 1/4 to 8/1, said thermally decomposable compound of beryllium decomposing during the heating of the coating composition to an oxide of beryllium.
In an electrode for electrochemical processes having an electrically conductive and relatively inert support at least the surface layer of which is of titanium or a titanium alloy, and an at least partial coating for said support, said coating being a protective and electrocatalytic layer obtained by heating on said support, in an oxidizing atmosphere at a temperature between 350.degree. and 800.degree. C., a coating composition consisting essentially of at least one thermally decomposable compound of iridium in a liquid vehicle, said iridium compound decomposing during the heating of the coating composition to provide said iridium in a metallic and/or oxide state, and at least one thermally decomposable compound of gallium, in an atomic ratio iridium/gallium of 1/4 to 8/1, said thermally decomposable compound of gallium decomposing during the heating of the coating composition to an oxide of gallium.
Dependencies are inferred from the claim text.