Chemical fixation of desulfurization residues
AssigneeWehran Engineering Corporation
InventorEugene P. Cocozza
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Abstract
Chemical fixation of industrial desulfurization residues by forming an intimate admixture of the desulfurization residue, such as a flue gas desulfurization sludge, with an alkaline calcination stack dust, such as a cement kiln dust, in the presence of sufficient water to provide a mass of workable consistency, adjusting the pH of the alkaline mass with acid, such as sulfuric or phosphoric acid, to a value of below about 7, e.g. in the acid range of from below about pH 7 down to about pH 5, and drying the pH adjusted mass to constant weight, preferably after forming the pH adjusted mass into a selectively shaped article, whereby to produce an environmentally stable and leach-resistant hardened solid, cement-like fixed product.
Claims35
Method for the chemical fixation of industrial desulfurization residues containing calcium and sulfur which result from the sulfur constituent removal treatment of gaseous effluent of basic manufacturing processes which comprises:
- admixing said desulfurization residues with an alkaline argillaceous and calcarious calcination stack dust and adjusting the pH of the resulting admixture with an inorganic acid to a value in the acid pH range below 7 in the presence of sufficient water to provide a mass of workable consistency, and;
- drying the pH adjusted mass to constant weight to produce an enviornmentally stable and leach resistant hardened solid product.
Dependencies are inferred from the claim text.