Thermite smelting of ferromolybdenum
AssigneeAmax Inc.
InventorsGeorge W. Clark, Douglas H. Dainty
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AssigneeAmax Inc.
InventorsGeorge W. Clark, Douglas H. Dainty
Estimating the term…
A process for producing ferromolybdenum alloys by thermite smelting of a particulated reaction mixture composed of a molybdenum oxide concentrate, an iron bearing material, a reductant and a slag fluxing agent present in controlled proportions. The reaction mixture is progressively charged into a refractory crucible and is exothermically reacted to produce a molten mass of ferromolybdenum alloy having a molten layer of slag floating on the upper surface thereof. The charging of the reaction mixture is interrupted for prescribed time intervals to permit the mass of ferromolybdenum alloy to solidify, and optionally, to permit a withdrawal of the major portion of the molten slag layer from the upper stratum thereof, whereby a multi-layered ingot is produced comprising layers of metallic ferromolybdenum separated by intervening residual slag layers.
A process for producing ferromolybdenum by a thermite smelting reaction which comprises the steps of forming a substantially uniform particulated mixture of molybdenum oxide, an iron bearing material, a reductant present in an amount substantially equal to the stoichiometric quantity required for reaction with the oxygen associated with said molybdenum oxide and said iron bearing material, and a slag fluxing agent, introducing a first portion of said mixture into a refractory crucible, igniting said first portion to effect an exothermic thermite reaction between said reductant and said molybdenum oxide and iron bearing material, progressively introducing a second portion of said mixture into said crucible to sustain said reaction forming a molten mass of said ferromolybdenum alloy having a first layer of slag floating on the upper surface thereof, interrupting the introduction of said mixture for a period of time to permit the migration of molten droplets of said ferromolybdenum alloy from said first slag layer into said molten mass, cooling said molten mass to effect a solidification thereof forming a first ferromolybdenum alloy button, progressively introducing a third portion of said mixture into said crucible on the molten slag layer to reinitiate and sustain said thermite reaction forming a second molten mass of ferromolybdenum alloy having a second slag layer thereon, cooling the reaction mass to effect a solidification of said second molten mass to form a second ferromolybdenum alloy button and second slag layer thereon, and thereafer extracting the solidified said reaction masses and separating said first and said second ferromolybdenum alloy button from said slag.
Dependencies are inferred from the claim text.